Studies of Optical, Morphological and Electrical Properties of POMA/PMMA Blends, Using Two Different Levels of Doping with CSA
Ceschin, Artemis M.; Sales, Maria J. A.; Pereira, Nizamara S.
http://dx.doi.org/10.1590/S0104-14282012005000051
Polímeros: Ciência e Tecnologia, vol.22, n4, p.384-389, 2012
Abstract
Poly(o-methoxyaniline) (POMA) was synthesized by oxidative polymerization of the monomer o-methoxyaniline. POMA/ poly(methyl methacrylate) (PMMA) blends were produced by dissolving both polymers in chloroform (CHCl3).The amount of camphor sulfonic acid (CSA) used as dopant of POMA was different, providing two methods for preparation of the blends. Solutions were analyzed by Fourier transform infrared spectroscopy (FTIR) and then deposited on glass substrate by spin coating for characterization by atomic force microscope (AFM) and current versus voltage (I × V) curves. FTIR spectra of solutions were similar as expected. In the AFM images a reduction and/or loss of globules common in conducting polymers (CP) such as polyaniline (PANI) and its derivatives was observed. Films produced with different amounts of CSA presented distinct, linear and non-linear I × V curves.
Keywords
POMA, CSA, PMMA, morphological, optical, electrical
References
1. Faez, R.; Rezende, M. C. & De Paoli, M. A. - Polímeros, 10, p.130
(2000). http://dx.doi.org/10.1590/S0104-14282000000300009
2. Bai, H. & Shi, G. - Sensors, 7, p.267 (2007). http://dx.doi.org/10.3390/ s7030267
3. Consolin Filho, N.; Leite, F. L.; Carvalho, E. R; Venâncio, E. C.; Vaz, C. M. P. & Mattoso, L. H. C. - J. Braz. Chem. Soc., 18, p.577 (2007). http://dx.doi.org/10.1590/S0103-50532007000300013
4. Bianchi, R. F.; Onmori, R. K. & Faria, R. M. - J. Polym. Sci., Part B: Polym. Phys., 43, p.74 (2005). http://dx.doi.org/10.1002/polb.20298
5. Brugnollo, E. D.; Paterno, L. G.; Leite, F. L.; Fonseca, F. J.; Constantino, C. J. L.; Antunes, P. A. & Mattoso, L. H. C. - Thin Solid Films, 516, p.3274 (2008). http://dx.doi.org/10.1016/j.tsf.2007.08.118
6. Tallman, D. E.; Spinks, G.; Dominis, A. & Wallace, G. G. - J. Solid State Electrochem., 6, p.73 (2002).
7. Gonçalves, D.; Santos, D. S.; Mattoso, L. H. C.; Karasz, F. E.; Akcelrud, L. & Faria, R. M. - Synth. Met., 90, p.5 (1997).
8. Norris, I. D.; Kane-Maguire, L. A. P.; Wallace, G. G. & Mattoso, L. H. C. - Aust. J. Chem., 53, p.89 (2000). http://dx.doi.org/10.1071/ CH00004
9. Norris, I. D.; Kane-Maguire, L. A. P. & Wallace, G. G. - Macromolecules, 33, p.3237 (2000). http://dx.doi.org/10.1021/ ma991339c
10. Melo, R. M.; Dantas, N. O.; Souza, N. C.; Oliveira Junior, O. N.; Faria, R. M. & Marletta, A. - Quim. Nova, 26, p.177 (2003). http://dx.doi. org/10.1590/S0100-40422003000200006
11. Souza, N. C.; Silva, J. R.; Rodrigues, C. A.; Costa, L. F.; Giacometti, J. A. & Oliveira Junior, O. N. – Thin Solid Films, 428, p.232 (2003).
12. Tale, A.; Passiniemib, P.; ForsCn’, O. & Ylasaari, S. - Synth. Met., 85, p.1333 (1997).
13. Rodrigues, P. C.; Muraro, M.; Garcia, C. M.; Souza, G. P.; Abbate, M.; Schreiner, W. H. & Gomes, M. A. B. - Eur. Polym. J., 37, p.2217 (2001). http://dx.doi.org/10.1016/S0014-3057(01)00104-5
14. Jousseaume, V.; Morsli, M. & Bonnet, A. - J. Appl. Polym. Sci., 84, p.1848 (2002). http://dx.doi.org/10.1002/app.10468
15. Jousseaume, V.; Morsli, M.; Bonnet, A.; Tesson, O. & Lefrant, S. - J. Appl. Polym. Sci., 67, p.1205 (1998). http://dx.doi.org/10.1002/ (SICI)1097-4628(19980214)67:7<1205::AID-APP6>3.0.CO;2-K
16. Mattoso, L. H. C. & Malmonge, L. F. - Polymer, 40, p.513 (1999). http://dx.doi.org/10.1016/S0032-3861(98)00280-8
17. Malmonge, L. F. & Mattoso, L. H. C. - Polímeros, 8, p.72 (1998).
18. Ram, M. K.; Carrara, S.; Paddeu, S.; MacCioni, P. E. & Nicolini, C. - Langmuir, 13, p.2760 (1997). http://dx.doi.org/10.1021/la960588g
19. Kulkarni, M. V. & Viswanath, A. K. - Sensors Actuat. B-Chem., 107, p.791 (2005).
20. Patil, R. C.; Ahmed, S. M.; Shiigi, H.; Nakayama, M. & Ogura, K. - J. Polym. Sci., Part A: Polym. Chem., 37, p.4596 (1999). http://dx.doi. org/10.1002/(SICI)1099-0518(19991215)37:24<4596::AID‑POLA17 >3.0.CO;2-7
21. Cheng, C.; Pavlinek, V.; He, Y.; Yan, Y.; Li, C. & Saha, P. - Smart Mater. Struct., 20, p.1 (2011).
22. Patil, D.; Patil, P.; Seo, Y. K. & Hwang, Y. K. - Sensors Actuat. B-Chem., 148, p.41 (2010).
23. Araujo, S. C. & Kawano, Y. - Polímeros, 11, p.213 (2001). http:// dx.doi.org/10.1590/S0104-14282001000400011
24. Zampronio, E. C. & Oliveira, H. P. - Mater. Res. Bull., 39, p.1525 (2004). http://dx.doi.org/10.1016/j.materresbull.2004.04.018
25. Jamal, R.; Abdiryim, T.; Ding, Y. & Nurlla, I. - J. Polym. Res., 15, p.75 (2008). http://dx.doi.org/10.1007/s10965-007-9145-3
26. Oliveira-César, M. A. F.; Zoioncz, S.; Oliveira, A. R. S.; Almeida, M. C. R.; Zawadzki, S. F.; Akcelrud, L.; Aguiar, M.; Tabak, D. & Lucas, E. F. - Polímeros, 9, p.157 (1999).
27. Oliveira, C. M. F.; Amorim, M. C. V. & Lucas, E. F. - Polímeros, 2, p.29 (1992).
28. Balamurugan, A.; Kannan, S.; Selvaraj, V. & Rajeswari, S. - Trends Biomater. Artif. Organs, 18, p.41 (2004).
29. Paterno, L. G. & Mattoso, L. H. C. - J. Appl. Polym. Sci., 83, p.1309 (2002). http://dx.doi.org/10.1002/app.2298
30. Paul, A.; Misra, T. N. & Talukdar, D. - Solid State Commun., 99, p.633 (1996). http://dx.doi.org/10.1016/0038-1098(96)00194-9
31. Rocha, I. S.; Mattoso, L. H. C.; Malmonge, L. F. & Gregório Junior, R. - J. Polym. Sci. Part B: Polym. Phys., 37, p.1219 (1999). http:// dx.doi.org/10.1002/(SICI)1099-0488(19990615)37:12<1219::AIDPOLB3> 3.0.CO;2-R
2. Bai, H. & Shi, G. - Sensors, 7, p.267 (2007). http://dx.doi.org/10.3390/ s7030267
3. Consolin Filho, N.; Leite, F. L.; Carvalho, E. R; Venâncio, E. C.; Vaz, C. M. P. & Mattoso, L. H. C. - J. Braz. Chem. Soc., 18, p.577 (2007). http://dx.doi.org/10.1590/S0103-50532007000300013
4. Bianchi, R. F.; Onmori, R. K. & Faria, R. M. - J. Polym. Sci., Part B: Polym. Phys., 43, p.74 (2005). http://dx.doi.org/10.1002/polb.20298
5. Brugnollo, E. D.; Paterno, L. G.; Leite, F. L.; Fonseca, F. J.; Constantino, C. J. L.; Antunes, P. A. & Mattoso, L. H. C. - Thin Solid Films, 516, p.3274 (2008). http://dx.doi.org/10.1016/j.tsf.2007.08.118
6. Tallman, D. E.; Spinks, G.; Dominis, A. & Wallace, G. G. - J. Solid State Electrochem., 6, p.73 (2002).
7. Gonçalves, D.; Santos, D. S.; Mattoso, L. H. C.; Karasz, F. E.; Akcelrud, L. & Faria, R. M. - Synth. Met., 90, p.5 (1997).
8. Norris, I. D.; Kane-Maguire, L. A. P.; Wallace, G. G. & Mattoso, L. H. C. - Aust. J. Chem., 53, p.89 (2000). http://dx.doi.org/10.1071/ CH00004
9. Norris, I. D.; Kane-Maguire, L. A. P. & Wallace, G. G. - Macromolecules, 33, p.3237 (2000). http://dx.doi.org/10.1021/ ma991339c
10. Melo, R. M.; Dantas, N. O.; Souza, N. C.; Oliveira Junior, O. N.; Faria, R. M. & Marletta, A. - Quim. Nova, 26, p.177 (2003). http://dx.doi. org/10.1590/S0100-40422003000200006
11. Souza, N. C.; Silva, J. R.; Rodrigues, C. A.; Costa, L. F.; Giacometti, J. A. & Oliveira Junior, O. N. – Thin Solid Films, 428, p.232 (2003).
12. Tale, A.; Passiniemib, P.; ForsCn’, O. & Ylasaari, S. - Synth. Met., 85, p.1333 (1997).
13. Rodrigues, P. C.; Muraro, M.; Garcia, C. M.; Souza, G. P.; Abbate, M.; Schreiner, W. H. & Gomes, M. A. B. - Eur. Polym. J., 37, p.2217 (2001). http://dx.doi.org/10.1016/S0014-3057(01)00104-5
14. Jousseaume, V.; Morsli, M. & Bonnet, A. - J. Appl. Polym. Sci., 84, p.1848 (2002). http://dx.doi.org/10.1002/app.10468
15. Jousseaume, V.; Morsli, M.; Bonnet, A.; Tesson, O. & Lefrant, S. - J. Appl. Polym. Sci., 67, p.1205 (1998). http://dx.doi.org/10.1002/ (SICI)1097-4628(19980214)67:7<1205::AID-APP6>3.0.CO;2-K
16. Mattoso, L. H. C. & Malmonge, L. F. - Polymer, 40, p.513 (1999). http://dx.doi.org/10.1016/S0032-3861(98)00280-8
17. Malmonge, L. F. & Mattoso, L. H. C. - Polímeros, 8, p.72 (1998).
18. Ram, M. K.; Carrara, S.; Paddeu, S.; MacCioni, P. E. & Nicolini, C. - Langmuir, 13, p.2760 (1997). http://dx.doi.org/10.1021/la960588g
19. Kulkarni, M. V. & Viswanath, A. K. - Sensors Actuat. B-Chem., 107, p.791 (2005).
20. Patil, R. C.; Ahmed, S. M.; Shiigi, H.; Nakayama, M. & Ogura, K. - J. Polym. Sci., Part A: Polym. Chem., 37, p.4596 (1999). http://dx.doi. org/10.1002/(SICI)1099-0518(19991215)37:24<4596::AID‑POLA17 >3.0.CO;2-7
21. Cheng, C.; Pavlinek, V.; He, Y.; Yan, Y.; Li, C. & Saha, P. - Smart Mater. Struct., 20, p.1 (2011).
22. Patil, D.; Patil, P.; Seo, Y. K. & Hwang, Y. K. - Sensors Actuat. B-Chem., 148, p.41 (2010).
23. Araujo, S. C. & Kawano, Y. - Polímeros, 11, p.213 (2001). http:// dx.doi.org/10.1590/S0104-14282001000400011
24. Zampronio, E. C. & Oliveira, H. P. - Mater. Res. Bull., 39, p.1525 (2004). http://dx.doi.org/10.1016/j.materresbull.2004.04.018
25. Jamal, R.; Abdiryim, T.; Ding, Y. & Nurlla, I. - J. Polym. Res., 15, p.75 (2008). http://dx.doi.org/10.1007/s10965-007-9145-3
26. Oliveira-César, M. A. F.; Zoioncz, S.; Oliveira, A. R. S.; Almeida, M. C. R.; Zawadzki, S. F.; Akcelrud, L.; Aguiar, M.; Tabak, D. & Lucas, E. F. - Polímeros, 9, p.157 (1999).
27. Oliveira, C. M. F.; Amorim, M. C. V. & Lucas, E. F. - Polímeros, 2, p.29 (1992).
28. Balamurugan, A.; Kannan, S.; Selvaraj, V. & Rajeswari, S. - Trends Biomater. Artif. Organs, 18, p.41 (2004).
29. Paterno, L. G. & Mattoso, L. H. C. - J. Appl. Polym. Sci., 83, p.1309 (2002). http://dx.doi.org/10.1002/app.2298
30. Paul, A.; Misra, T. N. & Talukdar, D. - Solid State Commun., 99, p.633 (1996). http://dx.doi.org/10.1016/0038-1098(96)00194-9
31. Rocha, I. S.; Mattoso, L. H. C.; Malmonge, L. F. & Gregório Junior, R. - J. Polym. Sci. Part B: Polym. Phys., 37, p.1219 (1999). http:// dx.doi.org/10.1002/(SICI)1099-0488(19990615)37:12<1219::AIDPOLB3> 3.0.CO;2-R
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