Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/S0104-14282011005000070
Polímeros: Ciência e Tecnologia
Scientific & Technical Article

A Study of the Initiator Concentration’s Effect on Styrene-Divinylbenzene Polymerization with Iron Particles

Conceição, Bárbara M. da; Costa, Marcos A. S.; Santa Maria, Luiz C. de; Silva, Manoel R.; Wang, Shu H.

Downloads: 0
Views: 1159

Abstract

This paper describes the preparation of magnetic copolymer obtained from suspension polymerization of styrene (Sty) and divinylbenzene (DVB) in the presence of iron particles treated and not treated with oleic acid. The magnetic copolymers were characterized according to their morphology, particle size distribution and magnetic properties. The results show that incorporation of iron particles significantly changed the particles’ morphology. All samples presented higher saturation magnetization than the values reported in the literature and the particle size distribution was more monodisperse when the polymerization was conducted with 5%wt of benzoyl peroxide (BPO).

Keywords

Magnetic copolymers, suspension polymerization, iron, composite

References

1. Denkbas, E. B.; Kiliçay, E.; Birlikseven, C. & Ozturk, E. - React. Funct. Polym., 50, p.225 (2002).

2. Lee, Y.; Rho, J. & Jung, B. - J. Appl. Polym. Sci., 89, p.2058 (2003). http://dx.doi.org/10.1002/app.12365

3. Liu, Z. L.; Ding, Z. H.; Yao, K. L.; Tao, J.; Du, G. H.; Lu, Q. H.; Wang, X.; Gong, F. L. & Chen, X. - J. Magn. Magn. Mater., 265, p.98 (2003).

4. Liu, X.; Ma, Z.; Xing, J. & Liu, H. - J. Magn. Magn. Mater., 270, p.1 (2004). http://dx.doi.org/10.1016/j.jmmm.2003.07.006

5. Ding, X. B.; Sun, Z. H.; Wan, G. X. & Jiang, Y. Y. - React. Funct. Polym., 38, p.11 (1998). http://dx.doi.org/10.1016/S1381- 5148(97)00154-5

6. Ugelstad, J.; Berge, A.; Ellingsen, T.; Schmid, R.; Nielsen, T. N.; Mork, P. C. - Prog. Polym. Sci., 17, p.87 (1992). http://dx.doi. org/10.1016/0079-6700(92)90017-S

7. Philippova, O.; Barabanova, A.; Molchanov, V. & Khokhlov, A. - Eur. Polym. J., 47, p.542 (2010). http://dx.doi.org/10.1016/j. eurpolymj.2010.11.006

8. Kroll, E.; Winnik, F. M. & Ziolo, R. F. - Chem. Mater., 8, p.1594 (1996). http://dx.doi.org/10.1021/cm960095x

9. Chen, L.; Yang, W. J. & Yang, C. Z. - J. Mater. Sci., 32, p.3571 (1997). http://dx.doi.org/10.1023/A:1018613926326

10. Käppler, T. E.; Hickstein, B.; Peuker, U. A & Posen C. - J. Biosci. Bioeng., 105, p.579 (2008). PMid:18640596. http://dx.doi.org/10.1263/ jbb.105.579

11. Amara, F.; Grinblat, J. & Margel, S. - J. Mater. Chem., 2010, 20, p.1899 (2010).

12. Ely, T. O.; Amiens, C. & Chaudret, B. - Chem. Mater., 11, p.526 (1999). http://dx.doi.org/10.1021/cm980675p

13. Horak, D.; Bohacek, J. & Subrt, M. - J. Polym. Sci., Part A: Polym. Chem., 38, p.1161 (2000).

14. Horak, D. - J. Polym. Sci., Part A: Polym. Chem., 39, p.3707(2001).

15. Liu, X.; Guan, Y.; Yang, Y.; Ma, Z.; Wu, X. & Liu, H. - J. Appl. Polym. Sci., 94, p.2205(2004). http://dx.doi.org/10.1002/app.21168

16. Liu, X.; Guan, Y.; Shen, R. & Liu, H. - J. Chromatogr. B, 822, p.91 (2005). PMid:15998604. http://dx.doi.org/10.1016/j.jchromb.2005.06.001

17. Yang, C.; Liu, H.; Guan, Y.; Xing, J.; Liu, J. & Shan, G. - J. Magn. Magn. Mater., 293, p.187(2005). http://dx.doi.org/10.1016/j. jmmm.2005.01.060

18. Yang, C.; Guan, Y.; Xing, J.; Liu, J.; Shan, G.; An, Z. & Liu, H. - Aiche J., 51, p.2011(2005). http://dx.doi.org/10.1002/aic.10467

19. Yang, C.; Guan, Y.; Xing, J.; Jia, G. & Liu, H. - React. Funct. Polym., 66, p.267 (2006). http://dx.doi.org/10.1016/j.reactfunctpolym.2005.08.012

20. Santa-Maria, L. C.; Leite, M. C. A. M.; Costa, M. A. S.; Ribeiro, J. M. S.; Senna, L. F. & Silva, M. R. - Eur. Polym. J., 39, p.843 (2003). PMid:14731290. http://dx.doi.org/10.1111/j.1365-2818.2004.01233.x

21. Santa-Maria, L. C.; Leite, M. C. A. M.; Costa, M. A. S.; Ribeiro, J. M. S.; Senna, L. F. & Silva, M. R. - J. Microsc., 213, p.94(2004).

22. Santa-Maria, L. C.; Leite, M. C. A. M.; Costa, M. A. S.; Ribeiro, J. M. S.; Senna, L. F. & Silva, M. R. - Mater. Lett., 58, p.3001(2004).

23. Alvarez, J. Alvarez, J. J. & Martinez, R. E. - J. Appl. Polym. Sci., 49, p.209 (1991). http://dx.doi.org/10.1002/app.1991.070490020

24. Ober, C. K. & Hair, M. L. - J. Polym. Sci., Part A: Polym. Chem., 25, p.1395 (1987). http://dx.doi.org/10.1002/pola.1987.080250516

25. Silverstein, R. M.; Bassler, G. C. & Morrill, T. C. - “Spectrometric Identification of Organic Compounds”, Guanabara Koogan S. A., Rio de Janeiro (1991).

26. Liu, X.; Guan, Y.; Liu, H.; Ma, Z.; Yang, Y. & Wu, X. - J. Magn. Magn. Mater., 293, p.111(2005). http://dx.doi.org/10.1016/j. jmmm.2005.01.051

27. Liu, X.; Guan, Y.; Ma, Z. & Liu, H. - Langmuir, 20, p.10278 (2004). PMid:15518525. http://dx.doi.org/10.1021/la0491908

28. Ma, Z.; Guan, Y.; Liu, X. & Liu, H. - J. Appl. Polym. Sci., 96, p.2174 (2005). http://dx.doi.org/10.1002/app.21688
588371737f8c9d0a0c8b48e2 polimeros Articles
Links & Downloads

Polímeros: Ciência e Tecnologia

Share this page
Page Sections