Adesivos Poliméricos à Base de SBR. 2. Influência de Diferentes Tipos de Agentes Promotores de Adesão
SBR-Based polymeric adhesives. Influence of different types of adhesion promoting agents
Pinto, Mauro E. C. B.; Visconte, Leila L. Y.; Nunes, Regina C. R.; Luz, Rinaldo F.
http://dx.doi.org/10.1590/S0104-14282011005000047
Polímeros: Ciência e Tecnologia, vol.21, n4, p.265-270, 2011
Resumo
Neste trabalho, foi desenvolvido um novo adesivo não estrutural à base de copolímero de SBR com alto teor em estireno (SBR‑53). O objetivo deste novo produto é avaliar a possibilidade de sua utilização no segmento moveleiro, em substituição ao adesivo de policloropreno (CR-M), cujo polímero-base é importado. Diferentes formulações de adesivos foram desenvolvidas, específicas para a indústria moveleira, e o desempenho do elastômero SBR-53 foi comparado ao dos elastômeros SBR-23 comercial (SBR tradicional – baixo teor de estireno) e CR-M, quanto à estabilidade em solução, viscosidade e propriedades mecânicas.
Palavras-chave
Adesivos, propriedades adesivas, copolímeros de butadieno-estireno
Abstract
In this work a new non-structural adhesive based on a high styrene content SBR copolymer (SBR-53) was developed. This new product is intended to be used in the furniture segment, to replace the chloroprene rubber (CR-M) adhesive, whose base polymer is imported. Different adhesive formulations were developed specifically for the furniture industry, and the performance of the elastomer SBR-53 was compared to that of commercial elastomers SBR-23 (low-styrene traditional SBR ) and CR-M, as for solution stability, viscosity and mechanical properties.
Keywords
Adhesives, adhesion properties, butadiene-styrene copolymers
References
1. Bhide, S. J.; Zurale, M. M. - “Adhesives and their novel applications”,
in: Proceedings of the 7° International Conference on Adhesion and
Adhesives - Adhesion’99, p.165, Cambridge - UK, set. (1999).
2. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.1, McGraw- Hill Companies, Inc., New York (2000).
3. Liesa, F.; Bilirlina, L. - “Adhesivos Industriales”, Marcombo S.A., Barcelona (1990).
4. Furtado, M. - “Adesivos: produtos avançados puxam o crescimento por vendas”. Quím. Deriv., 461 (2007).
5. Skeits, I.; Miron, J. - “Introduction to adhesives”, in: Handbook of adhesives, cap.1, I. Skeits (ed.), Van Nostrand Reinhold International Corporation Ltd., New York (1990).
6. Pocius, A. V. - “Adhesion and Adhesives Technology, An introduction”, cap.9, Hansen Gardner Publications, Inc., Maplewood (2002).
7. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.10, McGraw-Hill Companies, Inc., New York (2000).
8. Nesterova, L. A.; Reznichenko, S. V.; Lysova, G. A.; Sukhinin, N. S.; Morozov, Y. L. - Int. Polym. Sci. Technol., 29, p.41 (2002).
9. Graff, R. S. - “Neoprene”, in: Rubber Technology, cap. 12, M. Morton (ed.), Van Nostrand Reinhold, New York (1987).
10. Blomquist, R. F.; Mark, H. F.; Mcquetta, J. J.; Othmer, D. F., “Adhesives”, in- “Encyclopedia of Chemical Technology”, vol. 1, John Wiley & Sons, New York (1963).
11. Stewart, C. A.; Takeshita, T.; Coleman, M. L. - “Chloroprene Polymers”, in: Encyclopedia of Polymer Science and Engineering, vol.3, p. 442, H. F. Mark, N. M. Bikales, C. G. Overberger & G. Menges (eds.), John Wiley & Sons., New York (1985).
12. Morton, M. - “Rubber Technology”, Kluwer Academic Publishers, Inc., New York (1999).
13. Bretas, R. E. S.; D’Ávila, M. A. - “Reologia de Polímeros Fundidos”, EdUFSCar, São Paulo (2000).
14. Moore, M. - Rubber and Plast. News, 35, p.3 (2008).
15. Shaw, D. - Eur. Rubber J., 188, (4), p.21 (2006).
16. American Society For Testing And Materials - ASTM. - “ASTM D 1417 - Teor de sólidos totais”, in: Annual Book of ASTM Standards”, Section 9, vol. 09.01, ASTM, Philadelphia (1997).
17. American Society For Testing And Materials - ASTM. - “Annual Book of ASTM Standards, Standards relating to adhesives”, vol. 15.06, ASTM, Philadelphia (2005). ASTM D 2196, ASTM D 1876, ASTM D 1002.
18. Associação Brasileira de Normas Técnicas - ABNT. - “Norma ABNT NBR 15162: Adesivos - Determinação do tempo em aberto”, ABNT (2004).
19. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.4, McGraw- Hill Companies, Inc., New York (2000).
20. “Adesivos”, Borracha Atual, 48, p.18 (2003).
21. Brandley, H. L.; Day, G. L. - “Improved tire performance with solution SBR type polymers”, The Firestone Tire & Rubber Company, Ohio (1986).
22. McGrath, J. E. - “Anionic Polymerization: Kinetics, Mechanisms and Synthesis”, American Chemical Society, Washington (1981). http:// dx.doi.org/10.1021/bk-1981-0166
23. Pocius, A. V. - “Adhesion and Adhesives Technology, An introduction”, cap.7, Hansen Gardner Publications, Inc., Maplewood (2002).
24. Langerwerf, J. S. A. - Schuh-Tecnik, 6, p. 731 (1973).
25. Wadell, W.; Evans, L.; Gillick, J.; Shuttleworth, D. - Rubber Chem. Tech., 65, p. 687 (1992).
26. Airlie, C. D. - “Preparation of Tackfied SBR Polymer Adhesive Dispersions”, UK Patent Application GB 2137212 A, 22 mar. (1983).
27. White, L. - Eur. Rubber J., April, p. 24 (1997).
28. Jung, C. - “Adesivos base água: tendências de mercado e tecnologia”, in: Workshop Petroflex, Rio de Janeiro - RJ (2005).
29. Kampff, J. M. - “Panorama mundial e nacional da indústria de adesivos”, in: Workshop Petroflex, Rio de Janeiro - RJ (2005).
30. Gómez, M. J. P. - Rev. Plast. Mod., 83, p.142 (2002).
31. International Institute of Synthetic Rubber Producers. - “Emulsion styrene-butadiene rubber (E-SBR)”, Worldwide Polymers, Houston (2004).
2. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.1, McGraw- Hill Companies, Inc., New York (2000).
3. Liesa, F.; Bilirlina, L. - “Adhesivos Industriales”, Marcombo S.A., Barcelona (1990).
4. Furtado, M. - “Adesivos: produtos avançados puxam o crescimento por vendas”. Quím. Deriv., 461 (2007).
5. Skeits, I.; Miron, J. - “Introduction to adhesives”, in: Handbook of adhesives, cap.1, I. Skeits (ed.), Van Nostrand Reinhold International Corporation Ltd., New York (1990).
6. Pocius, A. V. - “Adhesion and Adhesives Technology, An introduction”, cap.9, Hansen Gardner Publications, Inc., Maplewood (2002).
7. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.10, McGraw-Hill Companies, Inc., New York (2000).
8. Nesterova, L. A.; Reznichenko, S. V.; Lysova, G. A.; Sukhinin, N. S.; Morozov, Y. L. - Int. Polym. Sci. Technol., 29, p.41 (2002).
9. Graff, R. S. - “Neoprene”, in: Rubber Technology, cap. 12, M. Morton (ed.), Van Nostrand Reinhold, New York (1987).
10. Blomquist, R. F.; Mark, H. F.; Mcquetta, J. J.; Othmer, D. F., “Adhesives”, in- “Encyclopedia of Chemical Technology”, vol. 1, John Wiley & Sons, New York (1963).
11. Stewart, C. A.; Takeshita, T.; Coleman, M. L. - “Chloroprene Polymers”, in: Encyclopedia of Polymer Science and Engineering, vol.3, p. 442, H. F. Mark, N. M. Bikales, C. G. Overberger & G. Menges (eds.), John Wiley & Sons., New York (1985).
12. Morton, M. - “Rubber Technology”, Kluwer Academic Publishers, Inc., New York (1999).
13. Bretas, R. E. S.; D’Ávila, M. A. - “Reologia de Polímeros Fundidos”, EdUFSCar, São Paulo (2000).
14. Moore, M. - Rubber and Plast. News, 35, p.3 (2008).
15. Shaw, D. - Eur. Rubber J., 188, (4), p.21 (2006).
16. American Society For Testing And Materials - ASTM. - “ASTM D 1417 - Teor de sólidos totais”, in: Annual Book of ASTM Standards”, Section 9, vol. 09.01, ASTM, Philadelphia (1997).
17. American Society For Testing And Materials - ASTM. - “Annual Book of ASTM Standards, Standards relating to adhesives”, vol. 15.06, ASTM, Philadelphia (2005). ASTM D 2196, ASTM D 1876, ASTM D 1002.
18. Associação Brasileira de Normas Técnicas - ABNT. - “Norma ABNT NBR 15162: Adesivos - Determinação do tempo em aberto”, ABNT (2004).
19. Petrie, E. M. - “Handbook of Adhesives and Sealants”, cap.4, McGraw- Hill Companies, Inc., New York (2000).
20. “Adesivos”, Borracha Atual, 48, p.18 (2003).
21. Brandley, H. L.; Day, G. L. - “Improved tire performance with solution SBR type polymers”, The Firestone Tire & Rubber Company, Ohio (1986).
22. McGrath, J. E. - “Anionic Polymerization: Kinetics, Mechanisms and Synthesis”, American Chemical Society, Washington (1981). http:// dx.doi.org/10.1021/bk-1981-0166
23. Pocius, A. V. - “Adhesion and Adhesives Technology, An introduction”, cap.7, Hansen Gardner Publications, Inc., Maplewood (2002).
24. Langerwerf, J. S. A. - Schuh-Tecnik, 6, p. 731 (1973).
25. Wadell, W.; Evans, L.; Gillick, J.; Shuttleworth, D. - Rubber Chem. Tech., 65, p. 687 (1992).
26. Airlie, C. D. - “Preparation of Tackfied SBR Polymer Adhesive Dispersions”, UK Patent Application GB 2137212 A, 22 mar. (1983).
27. White, L. - Eur. Rubber J., April, p. 24 (1997).
28. Jung, C. - “Adesivos base água: tendências de mercado e tecnologia”, in: Workshop Petroflex, Rio de Janeiro - RJ (2005).
29. Kampff, J. M. - “Panorama mundial e nacional da indústria de adesivos”, in: Workshop Petroflex, Rio de Janeiro - RJ (2005).
30. Gómez, M. J. P. - Rev. Plast. Mod., 83, p.142 (2002).
31. International Institute of Synthetic Rubber Producers. - “Emulsion styrene-butadiene rubber (E-SBR)”, Worldwide Polymers, Houston (2004).
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