Nanocompósitos de PVC com Argila Organicamente Modificada: Efeitos do Processamento e do Método de Incorporação da Argila
PVC/Organically Modified Montmorillonite Nanocomposites: Effects of Processing and Clay Incorporation Methodology
Mei, Lucia H. I.; Rodolfo Junior, Antonio
http://dx.doi.org/10.1590/S0104-14282009000100006
Polímeros: Ciência e Tecnologia, vol.19, n1, p.1-9, 2009
Resumo
Nanocompósitos de poli(cloreto de vinila) (PVC) flexível com argila organicamente modificada (O-MMT) foram preparados utilizando-se diferentes metodologias de produção, de forma a estudar seus efeitos sobre o grau de intercalação/esfoliação da argila. A morfologia dos nanocompósitos obtidos foi avaliada através de difratometria de raios X (DRX) e microscopia eletrônica de transmissão (MET). Foram também avaliadas propriedades de tração e estabilidade térmica estática das formulações preparadas. Nanocompósitos de microestrutura híbrida intercalada/parcialmente esfoliada foram obtidos, independentemente do composto de PVC ter sido processado a partir do pó ou granulado (extrudado previamente), e do método de incorporação da O-MMT à resina de PVC (diretamente no misturador intensivo ou pré-esfoliada em DIDP/OSE a quente). Os plastificantes, presentes na formulação do composto de PVC flexível, exerceram um papel importante no processo de intercalação e esfoliação da argila, facilitando a formação dos nanocompósitos.
Palavras-chave
PVC, poli(cloreto de vinila), nanocompósito polímero-argila
Abstract
Nanocomposites of poly(vinyl chloride) (PVC) and an organically modified montmorillonite (O-MMT) were prepared using different production approaches to assess possible effects on the degree of clay intercalation/exfoliation. The morphology of the nanocomposites was studied using X ray diffratometry and transmission electron microscopy. Tensile properties and static thermal stability were also evaluated. Hybrid intercalated/partially exfoliated nanocomposites were obtained, regardless of whether the PVC compound was processed from the powder (dry blend) or granulated (extruded) samples, or of the methodology used for incorporation of O-MMT into the PVC compound (directly in the intensive mixer or pre-exfoliated in a hot mixture of DIDP/ESO). The plasticizers, present in the flexible PVC compound, exerted an important role in the process of intercalation and exfoliation of the clay, helping the formation of the nanocomposites.
Keywords
PVC, poly(vinyl chloride), polymer/clay nanocomposites
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