Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/S0104-14282006000200006
Polímeros: Ciência e Tecnologia
Scientific & Technical Article

Electrochemical Studies on Inert Filler Incorporated Poly (Vinylidene Fluoride – Hexafluoropropylene) (PVDF – HFP) Composite Electrolytes

Kulandainathan, M. Anbu; Ravi, G.; Wilson, J.

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Abstract

The ionic conductivity, thermal stability and lithium transference number have been investigated in composite polymer electrolytes (CPE) of poly(vinylidene fluoride - hexafluoropropylene) (PVDF-HFP) incorporating nano fillers of AlO[OH]n or γ–Al2O3, with LiClO4 as salt. The compatibility of the composite polymer electrolyte with lithium metal anode has also been studied. The effect of particle size on the compatibility of Li/ CPE/ Li symmetric cells has also been analyzed.

Keywords

Ionic conductivity, compatibility, composite polymer electrolyte, transference number, thermal stability

References



1. Fray, F. M. - Solid polymer electrolytes - Fundamentals and Technological Applications, VCH (1993)

2. Scrosati, B.- Applications of Electroactive polymers, London: Chapman and Hall (1993).

3. Bertheir, C.; Gorecki, W.; Minier, M.; Armand, M. B.; Chanbagno, J. M. & Rigaud, P. - Solid State Ionics 11, p.91 (1983).

4. Gray, F. M.; MacCallum & Vincent, C. A. - Solid State Ionics, 18-19, p.225 (1986).

5. Bouridah, A.; Dalard, F.; Daroo, D.; Armand, M. B. - Solid State Ionics, 18-19, p.287 (1986).

6. Cameroon, G. G.; Harvie, J. A. & Ingram, M. D. - Solid State Ionics 34, p.65 (1986).

7. Gorecki, W.; Andreani, R.; Bertheir, C.; Armand, M.; Mali, M.; Roos, J. & Brinmann D - Solid State Ionics 18-19, p.295 (1986).

8. Chiodelli, G.; Ferlon, P.; Magistrio, A. & Saner, M. - Solid State Ionics 28-30, p.1009 (1988).

9. Bruce, P. G. & Vincent, C. A. - Solid State Ionics 40-41 p.607 (1990).

10. Bonino F.; Ottavini, M.; Scrosati, B. & Pistoia, G. - J. Electrochem. Soc., 135, p.12 (1988).

11. Croce, F. & Scrosati, B. - J. Power Sources 43-44, p.9 (1993).

12. Kim, D. W. - J. Power Sources 87, p.78, 87:78 (2000).

13. Abraham, K. M. & Alamgir, M. - J. Electrochem. Soc., 137, p.1657 (1990)

14. Manuel Stephan, A.; Thirunakaran, R.; Renganathan, N. G.; Muniyandi, N, & Ramesh Babu, B. - In: Radhakrishna Editor, Trends in Materials Science, Vol

1. Allied Publishers, p. 99

15. Iijima, Y.; Tyoguchi, Y. & Eda, N. - Denki Kagaku, 53, p.619 (1985).

16. Appetecchi, G. B,; Croce, F. & Scrosati, B. - Elecrochim. Acta, 40, p.991 (1995).

17. Abraham, K. M. & Alamgir, A. - J. Electrochem. Soc., 140, p.L96 (1993).

18. Mary Sukeshini, A.; Nishimoto, A. & Watanabe. M. - Solid State Ionics, 86-88, p.385 (1996).

19. Manuel Stephan, A.; Thirunakaran, R,; Renganathan, N. G.; Pitchumani, S.; Muniyandi, N. & Rama moorthy S, - J. Power Sources, 81- 82, p.752 (1999).

20. Manuel Stephan, A.; Prem Kumar, T.; Thirunakaran, R.; Renganathan, N. G.; Pitchumani, S. & Muniyanndi, N.- J. Power Sources, 89, p.80 (2000).

21. Choe, H. S.; Giaccami, J.; Alamgir, M, & Abraham, K. M. - Electrochim. Acta, 40, p.2289 (1995).

22. Song, J.Y.; Wang, Y. Y. & Wan C. C. – J. Power Sources , 77, p. 183 (1999).

23. Appetecchi, G. B.; Hassoun, J.; Scrosati, B.; Croce, F.; Cassel, F. & Salomon, M. - J. Power Sources, 124, p.246 (2003).

24. Croce, F.; Persi, L.; Scrosati, B.; Serraino-Fiory, F.; Plichta, E. & Hendrickson, M. A. - Electrochim. Acta, 46, p.2457 (2001).

25. Morita, M.; Fujisaki, T.; Yoshimoto, N. & Ishikawa, M. - Electrochim. Acta, 46, p.1565 (2001).

26. Singhal. R. G.; Capracotta, M. D.; Martin, J. D.; Khan, S. A. & Fedkiw, P. S. - J. Power Sources, 128, p.247 (2004).

27. Bloise, A. C.; Tambelli, C. C.; Franco, R. W. A.; Donoso, J. P.; Magon, C. J.; Souza, M. F.; Rasario, A. V. & Pereira, E.C.- Electrochim Acta, 46, p.1571 (2001).

28. Cheng, C. L.; Wan, C. C.; Wang, Y. Y. & Wu, M. S. - J. Power Sources, In Press (2005).

29. Bruce P. G. & Vincent C. A. - J. Electroanal. Chem., 1, p.225 (1987).

30. Watanabe, M.; Sanui, K.; Ogata, N.; Kobayashi, T. & Ohiaki, Z. - J. Appl. Phys., 57, p.123 (1985).

31. Binod, K.; Lawrance, G. & Scanlon, G. - J. Power Sources, 52, p.261 (1994).

32. Croce, F.; Appetecchi, G. B.; Perci, L. & Scrosati B. - Nature, 394, p.456 (1998).

33. Saika, D. & Kumar, A. - Electrochem Acta, 49, p.2581 (2004).

34. Liu Y.; Lee J. Y & Hong L. - J. Power Sources 129 p.303 (2004).

35. Qian, X.; Gu, N.; Cheng, Z.; Yang, X.; Wang, E. & Dong, S. - Electrochim. Acta 46, p.1829 (2001).

36. Croce, F.; Persi, L.; Scrosati, B.; Serraino-Fiory, F.; Plichta, E. & Hendrikson, M. A. - Electrochim.Acta 46 p.2457 (2001).

37. Capuoano, F.; Croce, F. & Scrosati, B. - J. Electrochem. Soc., 138,p.1918 (1991).

38. Fauteax, D. - J. Electrochem Soc. Proc. 94-28, p.379 (1994).

39. Kuratomi, J.; Iguchi, T.; Bando, T.; Aihara, Y.; Ono, T. & Kuwana, K. - J. Power Sources 97-98, p.801 (2001).

40. Kanamura, K.; Tamura, H.; Shiraishi, S. & Takehara, Z. - J. Electrochem. Soc. 142, p.340 (1995).

41. Evans, J.; Vincent, C. A. & Bruce, P. G. - Polymer 28, p.2325 (1987).

42. Nasef, M. M. & Saidi, H. - Mater. Chem. Phys., 25, In press (2005).
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