Mechanical Properties of N,N,N-trimethylchitosan Chloride Films
Assis, Odilio B. G.; Campana Filho, Sérgio P.; Britto, Douglas de
http://dx.doi.org/10.1590/S0104-14282005000200016
Polímeros: Ciência e Tecnologia, vol.15, n2, p.142-145, 2005
Abstract
Films of chitosan and N,N,N-trimethylchitosan were cast from aqueous solutions. Chitosan was dissolved in 1% acetic acid while deionized water was the solvent for N,N,N-trimethylchitosan chloride. The resulting films presented different mechanical behaviors as evaluated by DMTA. The film of chitosan exhibited an elastic-type behavior while that of N,N,N-trimethylchitosan was typically viscous. No glass transition temperatures were observed; however, a discrete thermal transition was detected at 25°C in the case of the N,N,N-trimethylchitosan.
Keywords
Chitosan, N,N,N-trimethylchitosan, mechanical properties
References
1. Ko, J.A.; Park, H.J.; Hwang, S.J.; Park, J.B.; Lee, J.S. - Int. J. Pharm. 249[1-2], p.165-174, (2002).
2. Pietrelli, L.; Xingrong, L. - Annali di Chimica. 94[5-6], p.389-398, (2004).
3. Agulló, E.; Rodríguez, M.S.; Ramos, V.; Albertengo, L. - Macromolecular Bioscience, 3[10], p. 521–530, (2003).
4. Assis, O.B.G.; Pessoa, J.D.C. – Braz. J. of Food Sci. Tech., 17[1], p.17-22, (2004).
5. Worrell, D. B.; Carrington, C. M. S.; Huber, D.J. - Post. Biol.Technol., 25, p.33-40, (2002).
6. Shahidi, F.; Arachchi, J.K.V.& Jeon, Y-J. - Trends in Food Scien. & Techn., 10, p.37 (1999).
7. Assis, O.B.G., Leoni, M.A. - Biotec. Ciência e Desenvolvimento. 30, p.33-38, (2003).
8. Möller, H., Grelier, S., Pardon, P., Coma, V. - J. Agric. Food Chem. 52, p. 6585-6591 (2004).
9. García, M.A.; Pinotti, A.; Martino, M.N.; Zaritzky, N.E. - Carbohyd. Polym., 56, p.339-345, (2002).
10. Bégin, A.; Calsteren, M.-R.V. - Inter. J. of Biolog. Macromol., 26, p.63-67, (1999).
11. Hwang, K.T.; Kim, J.T.; Jung, S.T.; Cho, G.S.; Park, H.J. – J. Appl. Polym. Sci., 89, p.3476-3484 (2003).
12. Srinivasa, P.C.; Ramesh, M.N.; Kumar, K.R.; Tharanathan, R.N. – J. Food Engineering, 63, p.79-85, (2004).
13. Miranda, S.P.; Garnica, O.; Lara-Sagahon, V.; Cárdenas, G. - J. Chil. Chem. Soc., 49, p.173-178, (2004).
14. Lazaridou, A.; Biliaderis, C.G. - Carbohyd. Polym., 48, p.179-190, (2002).
15. Britto,D. PhD Thesis, IQSC-USP, São Carlos, SP., 2003, 146p.
16. Curti,E.; Britto,D.; Campana Filho, S.P. - Macromol. Bioscience, 3, p.571-576 (2003).
17. Britto,D., Campana Filho,S.P. – Polym. Degrad. and Stability, 84, p.353-361, (2004).
18. Rathke, T.D.; Hudson, S.M. - J.M.S - Review Macromol. Chem. and Phys., v.C34, p.375-437, (1994).
19. Sakurai, K; Maegawa,T.; Takahashi, T. Polymer, 41, p.7051-7056, (2000).
20. Kim, S.S.; Kim, S.H.; Lee, Y.M.; - J. Polym. Sci.: Part B, Polym. Phys., 34, p.2367-2374, (1996).
21. Zong, Z.; Kimura, Y.; Takahashi, M.; Yamani, H. - Polymer, 41, p.899-906, (2000).]
Facebook
Google+
Twitter
LinkedIn
Mendeley
StumbleUpon
CiteULike
Reddit
Email