Preparation and Surface Analysis of PPY/SDBS Films on Aluminum Substrates
Scienza, Lisete C.; Thompson, George E.
http://dx.doi.org/10.1590/S0104-14282001000300014
Polímeros: Ciência e Tecnologia, vol.11, n3, p.142-148, 2001
Abstract
Polypyrrole films were generated on high purity aluminum substrates under anodic polarization from aqueous electrolytes comprised of pyrrole and sodium dodecylbenzene sulfonate. The methods employed to characterize the polymer films included scanning electron microscopy, Fourier-transform infrared and Xphotoelectron spectroscopy and X-ray diffraction. PPY/SDBS films revealed nodular morphology with occasional appearing of “dendrites”, high level of protonation, excess of counter-anions ([S]/[N] > [N+]/[N]) and high degrees of disorder.
Keywords
Polypyrrole films, aluminium, electrosynthesis
References
1. Arbizzani, C.; Matragostino, M. & Scrosati, B. - in Handbook of Organic Conductive Molecules and Polymers, H. S. Hawa, Ed; John Wiley & Sons, Chichester, Vol. 4, 595 (1997).
2. Scrosati, B. - Applications of Electroactive Polymers, Chapman & Hall, London (1993).
3. Araujo, W. S.; Margarit, I. C. P.; Ferreira, M.; Mattos, O. R. & Lima Neto, P. - Electrochimica Acta, 46,1307 (2001).
4. Fornari Jr., C. C. M.; Aeiyach, S.; Ferreira, C. A. - Anais do XII Simpósio Brasileiro de Eletroquímica e Eletroanalítica, Gramado, 141 (2001).
5. Moraes, S. R.; Vilca, D. H. & Motheo, A. J. - Anais do XII Simpósio Brasileiro de Eletroquímica e Eletroanalítica, Gramado, 822, (2001).
6. Scienza, L. C. & Thompson, G. E. - Anais do Latincorr'2000 ¾ 7th Ibero-American Congress of Corrosion Protection, Cartagena, paper 048-T06 (2000).
7. Lu, W-K and Elsebaumer, R. L. - Anais do Annual Technical Conference, 1276 (1998).
8. Kudoh, Y.; Fukuyama, M. & Yoshimura, S. - Synth. Met., 66,157 (1994).
9. Kanatzids, M. G. - Chemical Engineering News, 3, 36 (1990).
10. Rodrigues, J.; Otero, T. F.; Grande, H.; Moliton, J. P.; Moliton, A. & Trigaud, T. - Synth. Met., 76, 301 (1996).
11. Scienza, L. C. & Thompson, G. E. - in Anais do 13° Congresso Brasileiro de Engenharia e Ciência dos Materiais, Curitiba, 3899 (1998).
12. Hulse, P. & Beck, F. - J. Electrochem. Soc., 137, 2067 (1990).
13. Scienza, L. C.; Thompson, G. E. - in Anais do XII Simpósio Brasileiro de Eletroquímica e Eletroanalítica, Gramado, 481 (2001).
14. Vilca, D. H.; Moraes, S. R. & Motheo, A. J. - in Anais do XII Simpósio Brasileiro de Eletroquímica e Eletroanalítica, Gramado, 232 (2001).
15. Rodriguez, J.; Grande, H.-J. & Otero, T. F. - Handbook of Conducting Molecules and Polymers, H. S. Nawa, Ed; John Wiley & Sons, Chichester, Vol. 2, 415 (1997).
16. De Paoli, M. A.; Peres, R. C. D.; Panero, E. & Scrosati, B. - Electrochem. Acta, 37, 1173 (1992).
17. Mitchell, G. R. & Geri, A. - J. Phys. D: App. Phys., 20, 1346 (1987).
18. Ferreira, C. A.; Aeiyach, S.; Delamar, M. & Lacaze, P. C. - Surf. Interf. Anal., 20, 749 (1993).
19. Sutton, S. J. & Vaughan, A. S. - Polymer, 36, 1849 (1995).
20. Naoi, K.; Oura, Y.; Maeda, M. & Nakamura, S. - J. Electrochem. Soc., 142, 417. = 15 (1995)
21. Myrick, M. L.; Noll J. D. & Nicholson, M. A. - J. Electrochem. Soc., 1998, 145, 179.
22. Unsworth, J.; Innis, P. C.; Lunn, B. A.; Jin, Z. & Norton, G. P. - Synth. Met., 53, 59 (1992).
23. Su, W. & Iroh, J. O. - Polymer Preprints, 39, 159, (1998).
24. Iroh, J. O. & Su, W. - J Appl. Pol. Sc., 66, 2433 (1997).
25. Briggs, D. & Seah, M. P. - Practical Surface Analysis by Auger and X-ray Photo-electron Spectroscopy, John Wiley & Sons, Chichester, Vol. 3, 363 (1987).
26. Kang, E. T.; Neoh, K. G. & Tan, K. L. - Handbook of Conducting Molecules and Polymers, H. S. Nawa, Ed; John Wiley & Sons, Chichester, Vol. 3, 121 (1997).
27. Tan, K. L.; Tan, B. T. G. & Neoh, K. G.- J. Mat. Sc., 27, 4056 (1992).
28. Saunders, B. R.; Murray, K. S.; Fleming, R. J.; Cervini, R. & Allen, N. S. - in Handbook of Organic Conductive Molecules and Polymers, H. S. Nawa, Ed; John Wiley & Sons, Chichester, Vol. 3, 633 (1997).
29. Warren, L. F.; Walker, J. A.; Anderson, D. P.; Rhodes, C. G. & Buckey, L. J. - J. Electrochem. Soc., 36, 2286 (1989).
30. Wernet, W.; Monkenbusch, M. & Wegner, G. - Makromol. Chemie, Rap. Comm. 5, 157 (1984).
31. Wynne, R. J. & Street, G. B. - Macromolecules, 18, 2361 (1985).
32. Wegner, G. & Ruhe, J. - Faraday Discuss. Chem. Soc., 88, 333 (1989).
Facebook
Google+
Twitter
LinkedIn
Mendeley
StumbleUpon
CiteULike
Reddit
Email