Polímeros: Ciência e Tecnologia
Polímeros: Ciência e Tecnologia
Original Article

Use of pH-thermosensitive hydrogels for nickel ion removal and recovery

Andrés, Álvarez Casillas Cesar; Alberto, Cortés Ortega Jorge

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N-isopropylacrylamide / itaconic acid hydrogels were prepared in this study, varying the proportion of itaconic acid in the pregel mixture. The kinetics of the hydrogel swelling at 4 °C was determined, obtaining the kintetic patameters, in accordance with the second-order kinetic model. Similarly, the capacity to absorb water in terms of temperature was determined, along with the transition temperature of the samples. The influence of temperature on the capacity of the hidrogels to absorb nickel from aqueous solutions at 5% of NiCl2 and its subsequent recuperation was determined.


hydrogels, metals remover, recovery metals, pH-sensitive, thermosensitive.


1. Matlock, M. M., Howerton, B. S., & Atwood, D. A. (2002). Chemical precipitation of heavy metals from acid mine drainage. Water Research, 36(19), 4757-4764. PMid:12448518. http://dx.doi.org/10.1016/S0043-1354(02)00149-5.

2. Ito, A. (2000). Removal of heavy metals from anaerobically digested sewage sludge by a new chemical method using ferric sulfate. Water Research, 34(3), 751-758. http://dx.doi.org/10.1016/S0043-1354(99)00215-8.

3. Lefers, J. B., van den Broeke, W. F., Venderbosch, H. W., de Niet, J., & Kettelarij, A. (1987). Heavy metal removal from waste water from wet lime(stone)–gypsum flue gas desulfurization plants. Water Research, 21(11), 1345-1354. http://dx.doi.org/10.1016/0043-1354(87)90008-X.

4. Cerón Neculpan, M. S. (2006). Remoción de cadmio presente en aguas de desecho de la industria metal-mecánica mediante membranas líquidas emulsificadas en extractores del tipo estanque agitado en proceso batch. (Tesis memoria para optar al titulo de químico). Universidad de Chile, Chile.

5. Huang, P., Ye, Z., Xie, W., Chen, Q., Li, J., Xu, Z., & Yao, M. (2013). Rapid magnetic removal of aqueous heavy metals and their relevant mechanisms using nanoscale zero valent iron (nZVI) particles. Water Research, 12(47), 4050-4058. PMid:23566331. http://dx.doi.org/10.1016/j.watres.2013.01.054.

6. Xiang, L., Chan, L. C., & Wong, J. W. (2000). Removal of heavy metals from anaerobically digested sewage sludge by isolated indigenous iron-oxidizing bacteria. Chemosphere, 41(1–2), 283-287. PMid:10819212. http://dx.doi.org/10.1016/S0045-6535(99)00422-1.

7. Wu, Q., & Tian, P. (2008). Adsorption of Cu+2 Ions with Poly (N-isopropylacrylamide-co-methacrylic acid) Micro/Nanoparticles. Journal of Applied Polymer Science, 109(6), 3470-3476. http://dx.doi.org/10.1002/app.28450.

8. Bekiari, V., Sotiropoulou, M., Bokias, G., & Lianos, P. (2008). Use of poly(N,N-dimethylacrylamide-co-sodium acrylate) hydrogel to extract cationic dyes and metals from water. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 312(2–3), 214-218. http://dx.doi.org/10.1016/j.colsurfa.2007.06.053.

9. Ozay, O., Ekici, S., Baran, Y., Aktas, N., & Sahiner, N. (2009). Removal of toxic metal ions with magnetic hydrogels. Water Research, 43(17), 4403-4411. PMid:19625066. http://dx.doi.org/10.1016/j.watres.2009.06.058.

10. El Halah, A., Contreras, J., & López, F. (2011). Síntesis y aplicaciones de hidrogeles superabsorbentes de poli(acrilamida-co-monoitaconato de metoxietilo). Revista Latinoamericana de Metalurgia y Materiales, S3, 30-31.

11. Yildiz, U., Kemik, O. F., & Hazer, B. (2010). The removal of heavy metal ions from aqueous solutions by novel pH-sensitive hydrogels. Journal of Hazardous Materials, 183(1-3), 521-532. PMid:20709450. http://dx.doi.org/10.1016/j.jhazmat.2010.07.055.

12. Shibayama, M., Motonaga, T., & Nakamoto, C. (2001). Preparation pressure dependence of structure Inhomogeneities and dynamic fluctuations in poly(N-isopropylacrylamide). Gels Macromolecules, 34(4), 911-911. http://dx.doi.org/10.1021/ma001372v.

13. Biswas, C. S., Sulu, E., Hazer, B. (2014). Effect of the composition of methanol−water mixtures on tacticity of poly (N-ethylacrylamide) Gel Journal of Applied Polymer Science, 132, 41668-41678. http://dx.doi.org/10.1002/app.41668.

14. Biswas, C. S., & Hazer, B. (2015). Synthesis and characterization of stereoregular poly(N-ethylacrylamide) hydrogel by using Y(OTf)3 Lewis acid. Colloid & Polymer Science, 293(1), 143-152. http://dx.doi.org/10.1007/s00396-014-3399-1.

15. Cortés, J. A., Mendizábal, E., & Katime, I. (2008). Effect of comonomer type and concentration on the equilibrium swelling and volume phase transition temperature of N‐isopropylacrylamide‐based hydrogels. Journal of Applied Polymer Science, 108(3), 1792-1796. http://dx.doi.org/10.1002/app.27632.

16. Ortega, J. A. C. (2013). Synthesis of thermosensitive hydrogels of poly(N-isopropylacrylamide)-co-poly(N,N-dimethylacrylamide). Polímeros: Ciência e Tecnologia, 23(2), 189-195. http://dx.doi.org/10.4322/polimeros.2013.080.

17. Yıldız, U., & Hazer, B. (2000). Dispersion redox copolymerization of methyl methacrylate with macromonomeric azoinitiator as a macro crosslinker. Polymer, 41(2), 539-544. http://dx.doi.org/10.1016/S0032-3861(99)00217-7.

18. Fernandez, V. V. A., Tepale, N., Sánchez-Díaz, J. C., Mendizábal, E., Puig, J. E., & Soltero, J. F. A. (2006). Thermoresponsive nanostructured poly (N-isopropylacrylamide) hydrogels made via inverse microemulsion polymerization. Colloid & Polymer Science, 284(4), 387-395. http://dx.doi.org/10.1007/s00396-005-1395-1.

19. Katime, I., Velada, J. L., Novoa, R., Díaz de Apodaca, E., Puig, J., & Mendizabal, E. (1996). Swelling kinetics of Poly(Acrilamide)/Poly(mono-n-alkyl Itaconates) hydrogels. Polymer International, 40(4), 281-286. http://dx.doi.org/10.1002/(SICI)1097-0126(199608)40:4<281::AID-PI555>3.0.CO;2-H.

20. Bajpai, S. K., & Johnson, S. (2007). Removal of Ni+2 ions from aqueous solution by sorption into Poly(Acrylamide-co-Sodium Acrylate) hydrogels. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 44(3), 291-297. http://dx.doi.org/10.1080/10601320601077328.

21. Rojas de Gáscue, B., Ramírez, M., Prin, J.L., Torres, C., Bejarano, L., Villarroel, H., Rojas L., Murillo, M., & Katime, I. (2010). Hidrogeles de acrilamida/ácido acrilico y de acrilamida/poli(ácido acrilico): estudio de su capacidad de remediación en efluentes industriales. Revista Latinoamericana de Metalurgia y Materiales, 30(1), 28-39.

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