Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/0104-1428.20240025
Polímeros: Ciência e Tecnologia
Original Article

Properties of regenerated cellulose films with silver nanoparticles and plasticizersa

Lays Furtado de Medeiros Souza Kataoka; Maria del Pilar Hidalgo Falla; Sandra Maria da Luz

Downloads: 0
Views: 134

Abstract

Nanocomposite films from cellulose jute fibers can be promising for application in electronic devices, mainly when silver nanoparticles (AgNPs) are added, which increases their conductivity. This work studied the transmittance, conductivity, and thermal stability of regenerated cellulose films (RCF) by adding AgNPs and plasticizers. Carboxymethylcellulose (CMC), sorbitol, and glycerol plasticizers were incorporated at 15 wt.% and 0.5 wt.% of AgNPs. The resulting materials were studied using Ultraviolet-visible and Fourier Transform Infrared Spectroscopy, electrical analysis using the Van der Pauw method, and thermogravimetry. As a result, an average size of 9 nm for AgNPs was verified. Incorporating AgNP in the films decreased the transmittance by a minimum of 34% compared to pure RCF and reduced thermal stability by at least 10 ºC. Nanocomposites containing plasticizers showed an improved conductivity after incorporating these components, from 10-2 to 10-1 (S/cm).

 

 

Keywords

regenerated cellulose films, silver nanoparticles, transmittance, conductivity, thermal stability

References

1 Abdul Khalil, H. P. S., Bhat, A. H., & Ireana Yusra, A. F. (2012). Green composites from sustainable cellulose nanofibrils: a review. Carbohydrate Polymers, 87(2), 963-979. http://doi.org/10.1016/j.carbpol.2011.08.078.

2 Liu, X., Xiao, W., Ma, X., Huang, L., Ni, Y., Chen, L., Ouyang, X., & Li, J. (2020). Conductive regenerated cellulose film and its electronic devices – A review. Carbohydrate Polymers, 250, 116969. http://doi.org/10.1016/j.carbpol.2020.116969. PMid:33049865.

3 Kataoka, L. F. M. S., Hidalgo Falla, M. D. P., & Luz, S. M. (2021). The influence of potassium hydroxide concentration and reaction time on the extraction cellulosic jute fibers. Journal of Natural Fibers, 19(13), 6889-6901. http://doi.org/10.1080/15440478.2021.1934934.

4 Erdoğan, U. H., Seki, Y., Aydoğdu, G., Kutlu, B., & Akşit, A. (2016). Effect of different surface treatments on the properties of jute. Journal of Natural Fibers, 13(2), 158-171. http://doi.org/10.1080/15440478.2014.1002149.

5 Budtova, T., & Navard, P. (2016). Cellulose in NaOH–water based solvents: a review. Cellulose (London, England), 23(1), 5-55. http://doi.org/10.1007/s10570-015-0779-8.

6 Meera, K., & Ramesan, M. T. (2023). Development of high-performance biopolymer nanocomposites derived from carboxymethyl chitosan/boehmite via green synthesis. Polymer Composites, 44(3), 1135-1148. http://doi.org/10.1002/pc.27159.

7 Meera, K., Arun, K., & Ramesan, M. T. (2023). High performance biopolymer blend nanocomposites derived from cashew gum/polyvinyl alcohol/boehmite for flexible electronic devices. Journal of Applied Polymer Science, 140(7), e54300. http://doi.org/10.1002/app.54300.

8 Ramesan, M. T., Subburaj, M., Mathew, G., & Bahuleyan, B. K. (2023). Utilization of copper sulphide nanoparticles for the development of cashew tree gum/chitin biopolymer blend nanocomposites. Journal of Thermoplastic Composite Materials, 36(7), 984-1003. http://doi.org/10.1177/08927057211046282.

9 Kataoka, L. F. M. S., Leão, R. M., Gontijo, A. B., Falla, M. D. P. H., & Luz, S. M. (2022). Regenerated cellulose films from jute fibers applied in conductive nanocomposites. Materials Today. Communications, 33, 104645. http://doi.org/10.1016/j.mtcomm.2022.104645.

10 Cheremisinoff, N. P. (1998). Advanced polymer processing operations. USA: Noyes Publications.

11 Vanin, F. M., Sobral, P. J. A., Menegalli, F. C., Carvalho, R. A., & Habitante, A. M. Q. B. (2005). Effects of plasticizers and their concentrations on thermal and functional properties of gelatin-based films. Food Hydrocolloids, 19(5), 899-907. http://doi.org/10.1016/j.foodhyd.2004.12.003.

12 Callister, W. D., Jr. (2007). Materials science and engineering: an introduction. USA: John Wiley & Sons.

13 Meera, K., & Ramesan, M. T. (2023). Tailoring the performance of boehmite nanoparticles reinforced carboxymethyl chitosan/cashew gum blend nanocomposites via green synthesis. Polymer, 268, 125706. http://doi.org/10.1016/j.polymer.2023.125706.

14 Pang, J., Liu, X., Zhang, X., Wu, Y., & Sun, R. (2013). Fabrication of cellulose film with enhanced mechanical properties in ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). Materials (Basel), 6(4), 1270-1284. http://doi.org/10.3390/ma6041270. PMid:28809209.

15 Caraschi, J. C., & Campana, S. P., Fo. (1999). Influência do grau de substituição e da distribuição de substituintes sobre as propriedades de equilíbrio de carboximetilcelulose em solução aquosa. Polímeros: Ciência e Tecnologia, 9(2), 70-77. http://doi.org/10.1590/S0104-14281999000200015.

16 McHugh, T. H., & Krochta, J. M. (1994). Sorbitol- vs glycerol-plasticized whey protein edible films: integrated oxygen permeability and tensile property evaluation. Journal of Agricultural and Food Chemistry, 42(4), 841-846. http://doi.org/10.1021/jf00040a001.

17 Pérez, O. E., Sánchez, C. C., Pilosof, A. M. R., & Patino, J. M. R. (2008). Dynamics of adsorption of hydroxypropyl methylcellulose at the air-water interface. Food Hydrocolloids, 22(3), 387-402. http://doi.org/10.1016/j.foodhyd.2006.12.005.

18 Mali, S., Sakanaka, L. S., Yamashita, F., & Grossmann, M. V. E. (2005). Water sorption and mechanical properties of cassava starch films and their relation to plasticizing effect. Carbohydrate Polymers, 60(3), 283-289. http://doi.org/10.1016/j.carbpol.2005.01.003.

19 Leopold, N., & Lendl, B. (2003). A new method for fast preparation of highly surface-enhanced Raman scattering (SERS) active silver colloids at room temperature by reduction of silver nitrate with hydroxylamine hydrochloride. The Journal of Physical Chemistry B, 107(24), 5723-5727. http://doi.org/10.1021/jp027460u.

20 Wassei, J. K., & Kaner, R. B. (2010). Graphene, a promising transparent conductor. Materials Today, 13(3), 52-59. http://doi.org/10.1016/S1369-7021(10)70034-1.

21 Ma, X., Deng, Q., Wang, L., Zheng, X., Wang, S., Wang, Q., Chen, L., Huang, L., Ouyang, X., & Cao, S. (2019). Cellulose transparent conductive film and its feasible use in perovskite solar cells. RSC Advances, 9(17), 9348-9353. http://doi.org/10.1039/C9RA01301F. PMid:35520713.

22 Kaco, H., Zakaria, S., Chia, C. H., & Zhang, L. (2014). Transparent and printable regenerated kenaf cellulose/PVA film. BioResources, 9(2), 2167-2178. http://doi.org/10.15376/biores.9.2.2167-2178.

23 Yang, Q., Wang, F., Tang, K., Wang, C., Chen, Z., & Qian, Y. (2003). The formation of fractal Ag nanocrystallites via γ-irradiation route in isopropyl alcohol. Materials Chemistry and Physics, 78(2), 495-500. http://doi.org/10.1016/S0254-0584(02)00379-6.

24 Ludueña, L. N., Vecchio, A., Stefani, P. M., & Alvarez, V. A. (2013). Extraction of cellulose nanowhiskers from natural fibers and agricultural byproducts. Fibers and Polymers, 14(7), 1118-1127. http://doi.org/10.1007/s12221-013-1118-z.

25 Pourfarzad, A., Ahmadian, Z., & Habibi-Najafi, M. B. (2018). Interactions between polyols and wheat biopolymers in a bread model system fortified with inulin: a Fourier transform infrared study. Heliyon, 4(12), e01017. http://doi.org/10.1016/j.heliyon.2018.e01017. PMid:30560212.

26 Su, J.-F., Huang, Z., Yuan, X.-Y., Wang, X.-Y., & Li, M. (2010). Structure and properties of carboxymethyl cellulose/soy protein isolate blend edible films crosslinked by Maillard reactions. Carbohydrate Polymers, 79(1), 145-153. http://doi.org/10.1016/j.carbpol.2009.07.035.

27 Mondal, M. I. H., Yeasmin, M. S., & Rahman, M. S. (2015). Preparation of food grade carboxymethyl cellulose from corn husk agrowaste. International Journal of Biological Macromolecules, 79, 144-150. http://doi.org/10.1016/j.ijbiomac.2015.04.061. PMid:25936282.

28 Tavares, K. M., Campos, A., Luchesi, B. R., Resende, A. A., Oliveira, J. E., & Marconcini, J. M. (2020). Effect of carboxymethyl cellulose concentration on mechanical and water vapor barrier properties of corn starch films. Carbohydrate Polymers, 246, 116521. http://doi.org/10.1016/j.carbpol.2020.116521. PMid:32747230.

29 Ayala, G., Agudelo, A. C., & Vargas, R. (2012). Effect of glycerol on the electrical properties and phase behavior of cassava starch biopolymers. Dyna, 79(171), 138-147. Retrieved in 2024, March 24, from http://www.scielo.org.co/pdf/dyna/v79n171/a18v79n171.pdf

30 Van Der Pauw, L. J. (1958). A method of measuring specific resistivity and Hall effect of discs of arbitrary shapes. Philips Research Reports, 13(1), 1-9.

31 Choi, S. M., Han, S. S., & Shin, E. J. (2020). Highly stretchable conductive nanocomposite films using regenerated cellulose nanoparticles. ACS Applied Polymer Materials, 2(10), 4387-4398. http://doi.org/10.1021/acsapm.0c00294.

32 Prudêncio, L., Camilo, F. F., & Faez, R. (2014). Líquidos iônicos como plastificantes em blendas de borracha nitrílica/polianilina. Quimica Nova, 37(4), 618-623. http://doi.org/10.5935/0100-4042.20140103.

33 Liu, S., Yu, T., Wu, Y., Li, W., & Li, B. (2014). Evolution of cellulose into flexible conductive green electronics: A smart strategy to fabricate sustainable electrodes for supercapacitors. RSC Advances, 4(65), 34134-34143. http://doi.org/10.1039/C4RA07017H.

34 Zhao, D., Chen, C., Zhang, Q., Chen, W., Liu, S., Wang, Q., Liu, Y., Li, J., & Yu, H. (2017). High performance, flexible, solid-state supercapacitors based on a renewable and biodegradable mesoporous cellulose membrane. Advanced Energy Materials, 7(20), 1700739. http://doi.org/10.1002/aenm.201700739.

35 Tian, J., Peng, D., Wu, X., Li, W., Deng, H., & Liu, S. (2017). Electrodeposition of Ag nanoparticles on conductive polyaniline/cellulose aerogels with increased synergistic effect for energy storage. Carbohydrate Polymers, 156, 19-25. http://doi.org/10.1016/j.carbpol.2016.09.005. PMid:27842813.

36 Mun, S., Zhai, L., Min, S.-K., Yun, Y., & Kim, J. (2016). Flexible and transparent strain sensor made with silver nanowire-coated cellulose. Journal of Intelligent Material Systems and Structures, 27(8), 1011-1018. http://doi.org/10.1177/1045389X15577651.

37 Chen, J., Xu, J., Wang, K., Qian, X., & Sun, R. (2015). Highly thermostable, flexible, and conductive films prepared from cellulose, graphite, and polypyrrole nanoparticles. ACS Applied Materials & Interfaces, 7(28), 15641-15648. http://doi.org/10.1021/acsami.5b04462. PMid:26135618.

38 Lee, T.-W., & Jeong, Y. G. (2015). Regenerated cellulose/multiwalled carbon nanotube composite films with efficient electric heating performance. Carbohydrate Polymers, 133, 456-463. http://doi.org/10.1016/j.carbpol.2015.06.053. PMid:26344302.

39 Huang, H.-D., Liu, C.-Y., Zhang, L.-Q., Zhong, G.-J., & Li, Z.-M. (2015). Simultaneous reinforcement and toughening of carbon nanotube/cellulose conductive nanocomposite films by interfacial hydrogen bonding. ACS Sustainable Chemistry & Engineering, 3(2), 317-324. http://doi.org/10.1021/sc500681v.

40 Khan, A., Niazi, M. B. K., Naqvi, S. R., & Farooq, W. (2018). Influence of plasticizers on mechanical and thermal properties of methyl cellulose-based edible films. Journal of Polymers and the Environment, 26(1), 291-300. http://doi.org/10.1007/s10924-017-0953-1.

41 Silva, W. T. A. (2021). Espumas de poliestireno impregnadas com nanopartículas de prata para a redução catalítica de p-nitrofenol em água (Master's thesis). Universidade Estadual da Paraíba, Campina Grande.

42 Costa, F. S. (2016). Desenvolvimento de nanocompósitos de poli(3-hidroxibutirato-co-3-hidroxivalerato) com nanopartículas de prata (Master's thesis). Universidade Federal de São Paulo, São José dos Campos.
 

6712659ba953950b6a73e6f3 polimeros Articles
Links & Downloads

Polímeros: Ciência e Tecnologia

Share this page
Page Sections