Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/0104-1428.20240020
Polímeros: Ciência e Tecnologia
Original Article

Biodegradable hybrid PLA composites incorporating coffee husks and mineral fillers

Riquelme Gomes da Silva; Laysa Silva Barboza; Pedro Henrique Poubel Mendonça da Silveira; Marceli do Nascimento da Conceição; Roberto Carlos da Conceição Ribeiro; Daniele Cruz Bastos

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Abstract

This article details the development of hybrid composites with a PLA matrix filled with coffee husks, potassium feldspar, and Bahia Beige marble. Comprehensive analysis included FTIR, hardness, contact angle, density tests, SEM for microstructural insights, and XRF for optimizing raw material compositions. Also, variance analysis was applied in all results. The study revealed that these biodegradable composites hold promise for sustainable applications. Density variations were noted due to particle compaction, and hardness slightly decreased with coffee husks, attributed to uneven component distribution. Increased hydrophilicity was observed with filler addition. SEM confirmed strong interfacial adhesion, and color consistency was maintained. Notably, coffee husks significantly enhanced the degradation rate of PLA, achieving a 100% higher rate compared to pure PLA. The presence of calcium and potassium minerals offers additional benefits for soil health. The study suggests that thermoformed, multi-layered composite capsules can be fully biodegradable, promoting environmental sustainability in coffee capsule production.

 

 

Keywords

biodegradability, poly(lactic acid), polymer composite sustentability

References

1 Samoggia, A., & Busi, R. (2023). Sustainable coffee capsule consumption: understanding Italian consumers’ purchasing drivers. Frontiers in Sustainable Food Systems, 7, 1-13. http://doi.org/10.3389/fsufs.2023.1088877.

2 Samoggia, A., & Riedel, B. (2019). Consumers’ perceptions of coffee health benefits and motives for coffee consumption and purchasing. Nutrients, 11(3), 653. http://doi.org/10.3390/nu11030653. PMid:30889887.

3 Domingues, M. L. B., Bocca, J. R., Fávaro, S. L., & Radovanovic, E. (2020). Disposable coffee capsules as a source of recycled polypropylene. Polímeros, 30(1), e2020009. http://doi.org/10.1590/0104-1428.05518.

4 Nanni, A., Colonna, M., & Messori, M. (2022). Fabrication and characterization of new eco-friendly composites obtained by the complete recycling of exhausted coffee capsules. Composites Science and Technology, 222, 109358. http://doi.org/10.1016/j.compscitech.2022.109358.

5 Suaduang, N., Ross, S., Ross, G. M., Pratumshat, S., & Mahasaranon, S. (2019). Effect of spent coffee grounds filler on the physical and mechanical properties of poly(lactic acid) bio-composite films. Materials Today: Proceedings, 17(Part 4), 2104-2110. http://doi.org/10.1016/j.matpr.2019.06.260.

6 Otoukesh, M., Vera, P., Wrona, M., Nerin, C., & Es’haghi, Z. (2020). Migration of dihydroxyalkylamines from polypropylene coffee capsules to Tenax® and coffee by salt-assisted liquid–liquid extraction and liquid chromatography-mass spectrometry. Food Chemistry, 321, 126720. http://doi.org/10.1016/j.foodchem.2020.126720. PMid:32276149.

7 Cincotta, F., Tripodi, G., Merlino, M., Verzera, A., & Condurso, C. (2020). Variety and shelf-life of coffee packaged in capsules. Lebensmittel-Wissenschaft + Technologie, 118, 108718. http://doi.org/10.1016/j.lwt.2019.108718.

8 Garlotta, D. (2001). A literature review of poly(lactic acid). Journal of Polymers and the Environment, 9(2), 63-84. http://doi.org/10.1023/A:1020200822435.

9 Taib, N.-A. A. B., Rahman, M. R., Huda, D., Kuok, K. K., Hamdan, S., Bakri, M. K. B., Julaihi, M. R. M. B., & Khan, A. (2023). A review on poly lactic acid (PLA) as a biodegradable polymer. Polymer Bulletin, 80(2), 1179-1213. http://doi.org/10.1007/s00289-022-04160-y.

10 Ashothaman, A., Sudha, J., & Senthilkumar, N. (2023). A comprehensive review on biodegradable polylactic acid polymer matrix composite material reinforced with synthetic and natural fibers. Materials Today: Proceedings, 80(Part 3), 2829-2839. http://doi.org/10.1016/j.matpr.2021.07.047.

11 Swetha, T., Bora, A., Mohanrasu, K., Balaji, P., Raja, R., Ponnuchamy, K., Muthusamy, G., & Arun, A. (2023). A comprehensive review on polylactic acid (PLA): synthesis, processing and application in food packaging. International Journal of Biological Macromolecules, 234, 123715. http://doi.org/10.1016/j.ijbiomac.2023.123715. PMid:36801278.

12 Wu, Y., Gao, X., Wu, J., Zhou, T., Nguyen, T. T., & Wang, Y. (2023). Biodegradable polylactic acid and its composites: Characteristics, processing, and sustainable applications in sports. Polymers, 15(14), 3096. http://doi.org/10.3390/polym15143096. PMid:37514485.

13 Di Bartolo, A., Infurna, G., & Dintcheva, N. T. (2021). A review of bioplastics and their adoption in the circular economy. Polymers, 13(8), 1229. http://doi.org/10.3390/polym13081229. PMid:33920269.

14 Lima, A. M., Santos, M. C. C., Bastos, D. C., Libano, E. V. D. G., & Pereira, P. S. C. (2021). Polypropylene/sugarcane bagasse composites: influence of processing. Brazilian Journal of Development, 7(12), 110053-110065. http://doi.org/10.34117/bjdv7n12-002.

15 Chandgude, S., & Salunkhe, S. (2021). In state of art: mechanical behavior of natural fiber-based hybrid polymeric composites for application of automobile components. Polymer Composites, 42(6), 2678-2703. http://doi.org/10.1002/pc.26045.

16 Chagas, G. N., Barros, M. M., Leão, A. G., Tapanes, N. L. C. O., Ribeiro, R. C. C., & Bastos, D. C. (2022). A hybrid green composite for automotive industry. Polímeros, 32(2), e2022017. http://doi.org/10.1590/0104-1428.20220027.

17 Morelli, C. L., Pouzada, A. S., & Sousa, J. A. (2009). Influence of hybridization of glass fiber and talc on the mechanical performance of polypropylene composites. Journal of Applied Polymer Science, 114(6), 3592-3601. http://doi.org/10.1002/app.30980.

18 Hashemi, S. (2008). Hybridization effect on flexural properties of single- and double-gated injection moulded acrylonitrile butadiene styrene (ABS) filled with short glass fibres and glass beads particles. Journal of Materials Science, 43(14), 4811-4819. http://doi.org/10.1007/s10853-008-2683-1.

19 Carvalho, G. B., Canevarolo, S. V., Jr., & Sousa, J. A. (2020). Influence of interfacial interactions on the mechanical behavior of hybrid composites of polypropylene/short glass fibers/hollow glass beads. Polymer Testing, 85, 106418. http://doi.org/10.1016/j.polymertesting.2020.106418.

20 Lapčík, L., Maňas, D., Lapčíková, B., Vašina, M., Staněk, M., Čépe, K., Vlček, J., Waters, K. E., Greenwood, R. W., & Rowson, N. A. (2018). Effect of filler particle shape on plastic-elastic mechanical behavior of high density poly(ethylene)/mica and poly(ethylene)/wollastonite composites. Composites. Part B, Engineering, 141, 92-99. http://doi.org/10.1016/j.compositesb.2017.12.035.

21 Gerardo, C. F., França, S. C. A., Santos, S. F., & Bastos, D. C. (2020). A study of recycled high-density polyethylene with mica addition: influence of mica particle size on wetting behavior, morphological, physical, and chemical properties. International Journal of Developmental Research, 10(6), 37223-37228.

22 Hejna, A., Formela, K., & Saeb, M. R. (2015). Processing, mechanical and thermal behavior assessments of polycaprolactone/agricultural wastes biocomposites. Industrial Crops and Products, 76, 725-733. http://doi.org/10.1016/j.indcrop.2015.07.049.

23 Sung, S. H., Chang, Y., & Han, J. (2017). Development of polylactic acid nanocomposite films reinforced with cellulose nanocrystals derived from coffee silverskin. Carbohydrate Polymers, 169, 495-503. http://doi.org/10.1016/j.carbpol.2017.04.037. PMid:28504172.

24 Sanjay, M. R., Madhu, P., Jawaid, M., Senthamaraikannan, P., Senthil, S., & Pradeep, S. (2018). Characterization and properties of natural fiber polymer composites: a comprehensive review. Journal of Cleaner Production, 172, 566-581. http://doi.org/10.1016/j.jclepro.2017.10.101.

25 Hejna, A. (2021). Potential applications of by-products from the coffee industry in polymer technology: current state and perspectives. Waste Management, 121(3), 296-330. http://doi.org/10.1016/j.wasman.2020.12.018. PMid:33406477.

26 Sharma, R. K., Lakhani, R., & Tomar, P. (2018). A simple novel mix design method and properties assessment of foamed concretes with limestone slurry waste. Journal of Cleaner Production, 171, 1650-1663. http://doi.org/10.1016/j.jclepro.2017.10.073.

27 Barros, M. M., Oliveira, M. F. L., Ribeiro, R. C. C., Bastos, D. C., & Oliveira, M. G. (2020). Ecological bricks from dimension stone waste and polyester resin. Construction & Building Materials, 232, 117252. http://doi.org/10.1016/j.conbuildmat.2019.117252.

28 Malaquias, E. O., Pereira, A. A. M., Jr., Silveira, P. H. P. M., Altoé, L., & Teles, C. R. (2021). Uso de cálculo estequiométrico para avaliação da produção de biogás obtido da água residuária do café. Brazilian Journal of Production Engineering, 7(2), 48-58. http://doi.org/10.47456/bjpe.v7i2.34548.

29 American Society for Testing and Materials – ASTM. (2020).ASTM D792-20: standard test methods for density and specific gravity (relative density) of plastics by displacement. West Conshohocken: ASTM.

30 American Society for Testing and Materials – ASTM. (2021). ASTM D2240-15(2021): standard test method for rubber property-durometer hardness. West Conshohocken: ASTM.

31 Ribeiro, M. P., Neuba, L. M., Silveira, P. H. P. M., Luz, F. S., Figueiredo, A. B.-H. S., Monteiro, S. N., & Moreira, M. O. (2021). Mechanical, thermal and ballistic performance of epoxy composites reinforced with Cannabis sativa hemp fabric. Journal of Materials Research and Technology, 12, 221-233. http://doi.org/10.1016/j.jmrt.2021.02.064.

32 Acchar, W., Dultra, E. J. V., & Segadães, A. M. (2013). Untreated coffee husk ashes used as flux in ceramic tiles. Applied Clay Science, 75-76, 141-147. http://doi.org/10.1016/j.clay.2013.03.009.

33 Saikia, B. J., Parthasarathy, G., & Sarmah, N. C. (2008). Fourier transform infrared spectroscopic estimation of crystallinity in SiO2 based rocks. Bulletin of Materials Science, 31(5), 775-779. http://doi.org/10.1007/s12034-008-0123-0.

34 Manju, P., Krishnan, P. S. G., & Nayak, S. K. (2021). Effect of morphology and hydroxyl groups of different nanoparticles on the properties of PLA bionanocomposites. Materials Today: Proceedings, 41(Part 5), 1169-1174. http://doi.org/10.1016/j.matpr.2020.09.508.

35 Khan, A., Patidar, R., & Pappu, A. (2021). Marble waste characterization and reinforcement in low density polyethylene composites via injection moulding: towards improved mechanical strength and thermal conductivity. Construction & Building Materials, 269, 121229. http://doi.org/10.1016/j.conbuildmat.2020.121229.

36 Wang, N., Fu, Y., & Lim, L. (2011). Feasibility study on chemometric discrimination of roasted Arabica coffees by solvent extraction and Fourier transform infrared spectroscopy. Journal of Agricultural and Food Chemistry, 59(7), 3220-3226. http://doi.org/10.1021/jf104980d. PMid:21381653.

37 Wang, N., & Lim, L.-T. (2012). Fourier transform infrared and physicochemical analyses of roasted Coffee. Journal of Agricultural and Food Chemistry, 60(21), 5446-5453. http://doi.org/10.1021/jf300348e. PMid:22563854.

38 Marchi, B. Z., Silveira, P. H. P. M., Bezerra, W. B. A., Nascimento, L. F. C., Lopes, F. P. D., Candido, V. S., Silva, A. C. R., & Monteiro, S. N. (2023). Ballistic performance, thermal and chemical characterization of ubim fiber (Geonoma baculifera) reinforced epoxy matrix composites. Polymers, 15(15), 3220. http://doi.org/10.3390/polym15153220. PMid:37571114.

39 Reis, N., Franca, A. S., & Oliveira, L. S. (2013). Performance of diffuse reflectance infrared Fourier transform spectroscopy and chemometrics for detection of multiple adulterants in roasted and ground coffee. Lebensmittel-Wissenschaft + Technologie, 53(2), 395-401. http://doi.org/10.1016/j.lwt.2013.04.008.

40 Capek, P., Paulovičová, E., Matulová, M., Mislovičová, D., Navarini, L., & Suggi-Liverani, F. (2014). Coffea arabica instant coffee: chemical view and immunomodulating properties. Carbohydrate Polymers, 103, 418-426. http://doi.org/10.1016/j.carbpol.2013.12.068. PMid:24528749.

41 Ribeiro, J. S., Ferreira, M. M. C., & Salva, T. J. G. (2011). Chemometric models for the quantitative descriptive sensory analysis of Arabica coffee beverages using near infrared spectroscopy. Talanta, 83(5), 1352-1358. http://doi.org/10.1016/j.talanta.2010.11.001. PMid:21238720.

42 Craig, A. P., Botelho, B. G., Oliveira, L. S., & Franca, A. S. (2018). Mid infrared spectroscopy and chemometrics as tools for the classification of roasted coffees by cup quality. Food Chemistry, 245, 1052-1061. http://doi.org/10.1016/j.foodchem.2017.11.066. PMid:29287322.

43 Barrios-Rodríguez, Y., Collazos-Escobar, G. A., & Gutiérrez-Guzmán, N. (2021). ATR-FTIR for characterizing and differentiating dried and ground coffee cherry pulp of different varieties (Coffea arabica L.). Engenharia Agrícola, 41(1), 70-77. http://doi.org/10.1590/1809-4430-eng.agric.v41n1p70-77/2021.

44 Chieng, B. W., Ibrahim, N. A., Yunus, W. M. Z. W., & Hussein, M. Z. (2013). Poly(lactic acid)/poly(ethylene glycol) polymer nanocomposites: effects of graphene nanoplatelets. Polymers, 6(1), 93-104. http://doi.org/10.3390/polym6010093.

45 Wang, N., Zhang, X., Ma, X., & Fang, J. (2008). Influence of carbon black on the properties of plasticized poly (lactic acid) composites. Polymer Degradation & Stability, 93(6), 1044-1052. http://doi.org/10.1016/j.polymdegradstab.2008.03.023.

46 Angin, N., Caylak, S., Ertas, M., & Cavdar, A. D. (2022). Effect of alkyl ketene dimer on chemical and thermal properties of polylactic acid (PLA) hybrid composites. Sustainable Materials and Technologies, 32, e00386. http://doi.org/10.1016/j.susmat.2021.e00386.

47 Santos, R. S., Silveira, P. H. P. M., Bastos, B. C., Conceição, M. N., Ribeiro, R. C. C., & Bastos, D. C. (2023). Development of environmentally ecofriendly composites based on polypropylene/Bahia Beige Waste: effect of reinforcement content on physical, mechanical, chemical, and microstructural properties. Recent Progress in Materials, 5(3), 27. http://doi.org/10.21926/rpm.2303027.

48 Bakshi, P., Pappu, A., Bharti, D. K., & Patidar, R. (2021). Accelerated weathering performance of injection moulded PP and LDPE composites reinforced with calcium rich waste resources. Polymer Degradation & Stability, 192, 109694. http://doi.org/10.1016/j.polymdegradstab.2021.109694.

49 Ou, R., Xie, Y., Wolcott, M. P., Sui, S., & Wang, Q. (2014). Morphology, mechanical properties, and dimensional stability of wood particle/high density polyethylene composites: effect of removal of wood cell wall composition. Materials & Design, 58, 339-345. http://doi.org/10.1016/j.matdes.2014.02.018.

50 Silveira, P. H. P. M., Conceição, M. N., Pina, D. N., Paes, P. A. M., Monteiro, S. N., Tapanes, N. L. C. O., Ribeiro, R. C. C., & Bastos, D. C. (2024). Impact of different mineral reinforcements on HDPE COMPOSITES: effects of melt flow index and particle size on physical and mechanical properties. Polymers, 16(14), 2063. http://doi.org/10.3390/polym16142063. PMid:39065380.

51 Borsoi, C., Berwig, K. H., Scienza, L. C., Zoppas, B. C. D. A., Brandalise, R. N., & Zattera, A. J. (2014). Behavior in simulated soil of recycled expanded polystyrene/waste cotton composites. Materials Research, 17(1), 275-283. http://doi.org/10.1590/S1516-14392013005000167.

52 Coelho, K. V. S., Líbano, E. V. D. G., Ramos Filho, F. G., Santos, S. F., Pereira, P. S. C., & Bastos, D. C. (2021). Development of wood plastic composite with reduced water absorption. International Journal of Developmental Research, 11(2), 44547-44551.

53 Kadea, S., Kittikorn, T., & Hedthong, R. (2024). Sustainable laminate biocomposite of wood pulp/PLA with modified PVA-MFC compatibilizer: weathering resistance and biodegradation in soil. Industrial Crops and Products, 218, 118913. http://doi.org/10.1016/j.indcrop.2024.118913.

54 Siakeng, R., Jawaid, M., Asim, M., & Siengchin, S. (2020). Accelerated weathering and soil burial effect on biodegradability, colour and texture of coir/pineapple leaf fibres/PLA biocomposites. Polymers, 12(2), 458. http://doi.org/10.3390/polym12020458. PMid:32079111.

55 Jaramillo, L. Y., Vásquez-Rendón, M., Upegui, S., Posada, J. C., & Romero-Sáez, M. (2021). Polyethylene-coffee husk eco-composites for production of value-added consumer products. Sustainable Environment Research, 31(1), 34. http://doi.org/10.1186/s42834-021-00107-6.

56 Petinakis, E., Yu, L., Simon, G. P., Dai, X. J., Chen, Z., & Dean, K. (2014). Interfacial adhesion in natural fiber‐reinforced polymer composites. In V. K. Thakur (Ed.), Lignocellulosic polymer composites: processing, characterization, and properties (pp. 17-39). Massachusetts: Scrivener Publishing LLC. http://doi.org/10.1002/9781118773949.ch2.

57 Almeida, P. O., Gerardo, C. F., de Leão, A. G., França, S. C. A., Santos, S. F., & Bastos, D. C. (2021). Sustainable composites based on recycled high-density polyethylene/mica. Materials Research, 24(2), e20200418. http://doi.org/10.1590/1980-5373-mr-2020-0418.

58 Silveira, P. H. P. M., Santos, M. C. C., Chaves, Y. S., Ribeiro, M. P., Marchi, B. Z., Monteiro, S. N., Gomes, A. V., Tapanes, N. L. C. O., Pereira, P. S. C., & Bastos, D. C. (2023). Characterization of thermo-mechanical and chemical properties of polypropylene/hemp fiber biocomposites: impact of maleic anhydride compatibilizer and fiber content. Polymers, 15(15), 3271. http://doi.org/10.3390/polym15153271. PMid:37571165.

59 Acosta, A. P., Amico, S. C., Delucis, R. A., Missio, A. L., Rodrigues, M. B. B., Ribeiro, A. C. R., Goularte, M. P., & Gatto, D. A. (2024). Surface analysis of different wood polymer composites exposed to artificial weathering. Journal of Wood Chemistry and Technology, 44(2), 88-101. http://doi.org/10.1080/02773813.2023.2299814.

60 Melgosa, M., Ruiz-López, J., Li, C., García, P. A., Della Bona, A., & Pérez, M. M. (2020). Color inconstancy of natural teeth measured under white light-emitting diode illuminants. Dental Materials, 36(12), 1680-1690. http://doi.org/10.1016/j.dental.2020.10.001. PMid:33172605.

61 Mitchell, M. K., & Hirt, D. E. (2015). Degradation of PLA fibers at elevated temperature and humidity. Polymer Engineering and Science, 55(7), 1652-1660. http://doi.org/10.1002/pen.24003.

62 Vasile, C., Pamfil, D., Rapa, M., Darie-Nit, R. N., Mitelut, A. C., Popa, E. E., Popescu, P. A., Draghici, M. C., & Popa, M. E. (2018). Study of the soil burial degradation of some PLA/CS biocomposites. Composite B Engineering, 142, 251-262. http://doi.org/10.1016/j.compositesb.2018.01.026.
 

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