Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/0104-1428.20220010
Polímeros: Ciência e Tecnologia
Original Article

Study of mechanical properties of inner tubes exposed to gamma radiationa

Sandra Regina Scagliusi; Elizabeth Leite Carvalho Cardoso; Fabio José Esper; Ademar Benevólo Lugão; Helio Wiebeck

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Abstract

Due to the technical evolution of tires, currently most automotive tires do not have an inner tube. However, truck, motorcycle and bicycle tires still use tires with inner tubes, mostly made of synthetic elastomeric material, which guarantees good potential for air restriction or longer periods for tire pressure failure. This work aims to study changes in the mechanical properties of a truck inner tire, after its exposure to gamma rays, to promote the subsequent recycling of the material. The choice of ionizing radiation is due to its ability to modify the structure and properties of materials, in addition to its applicability in recycling/recovering rubber. For the characterization of the samples, doses of 5, 10, 15, 20, 25 and 30 kGy were applied, and after irradiation as a sample, they were tested using the following characterization methods: traction and elongation at break, hardness, thermal aging and elemental analysis. Observed that is a decrease in the values of the mechanical properties of the samples after irradiation, mainly at doses greater than 10 kGy.

 

 

Keywords

gamma rays, inner tubes, mechanical properties, rubber

References

1 Arima, S., & Battaglia, A. (2003). Logística reversa – da terra para a terra, uma visão do ciclo total. Revista Tecnologística, 91, 134-141.

2 Ramos, L. S. N. (2005). A Logística Reversa de Pneus Inservíveis: O problema da Localização dos Pontos de Coleta (Master’s thesis). Universidade Federal de Santa Catarina, Florianópolis.

3 Kamimura, E. (2004). Potencial dos resíduos de borracha de pneus pela indústria da construção civil (Master’s thesis). Universidade Federal de Santa Catarina, Florianópolis.

4 Michelin. (2021, June 22). Retrieved in 2022, Juy 04, from https://thetiredigest.michelin.com/an-unknown-object-the-tire-materials.

5 Rippel, M. M., & Bragança, F. C. (2009). Natural rubber and nanocomposites with clay. Quimica Nova, 32(3), 818-826. http://dx.doi.org/10.1590/S0100-40422009000300024.

6 Faustino, O. W. C., & Leite, E. F. (2014). Desenvolvimento sustentável e o fênomeno do empreendedorismo com pneus inservíveis: um estudo de caso na “Pneu Verde”. Holos, 5, 344-360. http://dx.doi.org/10.15628/holos.2014.1420.

7 Green Car Congress. (2020). USTMA report finds that recycling of end-of-life tires dropped from 96% in 2013 to 76% in 2019. Retrieved in 2022, Juy 04, from https://www.greencarcongress.com/2020/10/20201015-ustma.html.

8 Viotti, M. A. P., Araújo, J. A., & Oliveira, F. A. (2017). Avaliação do sistema Gerenciamento de Pneus para o município de Volta Redonda. Cadernos UniFOA, 12(33), 7-16. http://dx.doi.org/10.47385/cadunifoa.v12.n33.444.

9 Tire Business. (2018). 2018 Global Tire Company RankingsTire Business. Retrieved in 2022, Juy 04, from https://www.tirebusiness.com/assets/PDF/TB117299928.PDF.

10 Saron, C. (2016). Reciclagem de pneus. Revista FAPESP. Retrieved in 2022, Juy 04, from https://revistapesquisa.fapesp.br/reciclagem-de-pneus/.

11 Erman, B., Mark, J. E., & Roland, C. M., editors (2013). The science and technology of rubber. Amsterdam: Elsevier.

12 Rodgers, B., & Waddell, W. (2013). The science of rubber composition. In B. Erman, J. E. Mark, & C. M. Roland (Eds). The science and technology of rubber (pp. 417-471). Amsterdam: Elsevier. http://dx.doi.org/10.1016/B978-0-12-394584-6.00009-1.

13 Beretta, E. M., Aguiar, J. P. O., Lauzer, M. B., Picoli, J. I., & Troncoso, S. M. T. (2014). Reaproveitamento da câmara do pneu de bicicletas: parâmetros para corte e gravação a laser. In 11º Congresso Brasileiro de Pesquisa e Desenvolvimento em Design (pp. 2056-2067). Gramado: Blucher Design Proceedings. http://dx.doi.org/10.5151/designpro-ped-00911.

14 Karaağaç, B., Şen, M., Deniz, V., & Güven, O. (2007). Recycling of gamma irradiated inner tubes in butyl based rubber compounds. Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms, 265(1), 290-293. http://dx.doi.org/10.1016/j.nimb.2007.08.061.

15 Charlesby, A. (1953). Effect of High-energy Radiation on Long-chain Polymers. Nature, 171(4343), 167. http://dx.doi.org/10.1038/171167a0.

16 Bhattacharya, A. (2000). Radiation and industrial polymers. Progress in Polymer Science, 25(3), 371-401. http://dx.doi.org/10.1016/S0079-6700(00)00009-5.

17 Zaharescu, T., Postolache, C., & Giurginca, M. (1996). The structural changes in butyl and halogenated butyl elastomers during gamma irradiation. Journal of Applied Polymer Science, 59(6), 969-974. http://dx.doi.org/10.1002/(SICI)1097-4628(19960207)59:6<969::AID-APP9>3.0.CO;2-N.

18 Kamachi, M. (1987). ESR studies on radical polymerization. In Polymer physics. Advances in polymer science (pp. 207-275). Germany: Springer,Berlin, Heidelberg. http://dx.doi.org/10.1007/BFb0024045.

19 Karmanova, O. V., Tikhomirov, S. G., Kayushnikov, S. N., Shashok, Z. S., & Polevoy, P. S. (2019). Obtaining and using of reclaimed butyl rubber with the use of ionizing radiation. Radiation Physics and Chemistry, 159, 154-158. http://dx.doi.org/10.1016/j.radphyschem.2019.02.038.

20 Chen, H.-B., Wang, P.-C., Liu, B., Zhang, F.-S., & Ao, Y.-Y. (2018). Gamma irradiation induced effects of butyl rubber based damping material. Radiation Physics and Chemistry, 145, 202-206. http://dx.doi.org/10.1016/j.radphyschem.2017.11.001.

21 Flory, P. J., & Rehner, J., Jr. (1943). Statistical mechanics of Cross‐Linked Polymer Networks II. Swelling. The Journal of Chemical Physics, 11(11), 521-526. http://dx.doi.org/10.1063/1.1723792.

22 Brandrup, J., Immergut, E. H., & Grulke, E. A., editors (2003). Polymer handbook. New York: Wiley.

23 Seguchi, T., Arakawa, K., Ito, M., Hayakawa, N., & Machi, S. (1983). Radiation induced oxidative degradation of polymers—III. Effect of radiation on mechanical properties. Radiation Physics and Chemistry, 21(6), 495-501.
 

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