Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.1590/0104-1428.20220009
Polímeros: Ciência e Tecnologia
Original Article

Poly(methyl methacrylate) and silica nanocomposites as new materials for polymeric optical devices

Rafael Affonso Netto; Fabrícia Faria de Menezes; Rubens Maciel Filho; Julio Roberto Bartoli

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Abstract

PMMA is one of the most used polymers for optical applications, due to its well-known optical properties and low-cost. PMMA/fumed silica nanocomposites were synthesized by in situ polymerization under sonication to produce optical materials using two types of silica, a PDMS surface-modified and an unmodified one. Silica content and sonication amplitude effects on nanocomposites properties were studied by factorial experimental designs. Nanocomposites retained the high transparency of pristine PMMA, especially at lower levels of silica and sonication. Rheological analysis indicated better dispersion of the unmodified silica in PMMA. Dispersed silica in the PMMA nanocomposites decreased the PMMA refractive index by 0.012, making PMMA/fumed silica suitable for the cladding layer of PMMA-core waveguides, resulting in the total reflectance phenomenon for light guiding. Therefore, PMMA/fumed silica nanocomposites provide promising materials for polymer optical devices, such as optical fibers and panels, optical sensors and biosensors, photonic platforms, daylighting, and multi-touchscreen displays.

 

 

Keywords

polymer optical fibers, in situ polymerization, fumed silica, sonication, rheology

References

1 Ishigure, T., Horibe, A., Nihei, E., & Koike, Y. (1995). High-bandwidth, high-numerical aperture graded-index polymer optical fiber. Journal of Lightwave Technology, 13(8), 1686-1691. http://dx.doi.org/10.1109/50.405310.

2 Bartoli, J. R. (2000). Development and characterization of graded-index polymeric films for optical guides and sensors. In 14th International International Conference on Optical Fiber Sensors (pp. 838-841). Bellingham: Society of Photo-Optical Instrumentation Engineers.

3 Peng, G.-D., Ji, P. N., & Wang, T. (2004). Development of special polymer optical fibers and devices. In: Proceedings of SPIE 5595: Active and Passive Optical Components for WDM Communications IV (pp. 138-152) Bellingham: Society of Photo-Optical Instrumentation Engineers.

4 Giacon, V. M., Padilha, G. S., & Bartoli, J. R. (2015). Fabrication and characterization of polymeric optical by plasma fluorination process. Optik, 126(1), 74-76. http://dx.doi.org/10.1016/j.ijleo.2014.08.152.

5 Kaino, T., Fujiki, M., & Nara, S. (1981). Low-loss polystyrene core-optical fibers. Journal of Applied Physics, 52(12), 7061-7063. http://dx.doi.org/10.1063/1.328702.

6 van Eijkelenborg, M. A., Argyros, A., & Leon-Saval, S. G. (2008). Polycarbonate hollow-core microstructured optical fiber. Optics Letters, 33(21), 2446-2448. http://dx.doi.org/10.1364/OL.33.002446. PMid:18978882.

7 Cordeiro, C. M. B., Ng, A. K. L., & Ebendorff-Heidepriem, H. (2020). Ultra-simplified single-step fabrication of microstructured optical fiber. Scientific Reports, 10(1), 9678. http://dx.doi.org/10.1038/s41598-020-66632-3. PMid:32541807.

8 Faiz, F., Baxter, G., Collins, S., Sidiroglou, F., & Cran, M. (2020). Polyvinylidene fluoride coated optical fibre for detecting perfluorinated chemicals. Sensors and Actuators. B, Chemical, 312, 128006. http://dx.doi.org/10.1016/j.snb.2020.128006.

9 Koike, Y., & Ishigure, T. (2006). High-bandwidth plastic optical fiber for fiber to the display. Journal of Lightwave Technology, 24(12), 4541-4553. http://dx.doi.org/10.1109/JLT.2006.885775.

10 Ferreira, R. A. S., André, P. S., & Carlos, L. D. (2010). Organic–inorganic hybrid materials towards passive and active architectures for the next generation of optical networks. Optical Materials, 32(11), 1397-1409. http://dx.doi.org/10.1016/j.optmat.2010.06.019.

11 Benabid, F., Knight, J. C., Antonopoulos, G., & Russell, P. S. J. (2002). Stimulated Raman scattering in hydrogen-filled hollow-core photonic crystal fiber. Science, 298(5592), 399-402. http://dx.doi.org/10.1126/science.1076408. PMid:12376698.

12 Sharma, D. K., Sharma, A., & Tripathi, S. M. (2018). Thermo-optic characteristics of hybrid polymer/silica microstructured optical fiber: an analytical approach. Optical Materials, 78, 508-520. http://dx.doi.org/10.1016/j.optmat.2018.02.037.

13 Li, C.-P., Tenent, R. C., & Wolden, C. A. (2020). Optical and mechanical properties of nanocomposite films based on Polymethyl Methacrylate (PMMA) and fumed silica nanoparticles. Polymer Engineering and Science, 60(3), 553-557. http://dx.doi.org/10.1002/pen.25312.

14 Anandhan, S., & Bandyopadhyay, S. (2011). Polymer nanocomposites: from synthesis to applications. In J. Cuppoletti (Ed.), Nanocomposites and polymers with analytical methods (pp. 1-28). London: IntechOpen. http://dx.doi.org/10.5772/17039.

15 Zhang, Y., & Luo, Y. (2021). Naturally derived nanomaterials for multidisciplinary applications and beyond. ES Food & Agroforestry, 4, 1-2. http://dx.doi.org/10.30919/esfaf484.

16 Islam, M. J., Rahman, M. J., & Mieno, T. (2020). Safely functionalized carbon nanotube–coated jute fibers for advanced technology. Advanced Composites and Hybrid Materials, 3(3), 285-293. http://dx.doi.org/10.1007/s42114-020-00160-6.

17 Lewicki, J. P., Rodriguez, J. N., Zhu, C., Worsley, M. A., Wu, A. S., Kanarska, Y., Horn, J. D., Duoss, E. B., Ortega, J. M., Elmer, W., Hensleigh, R., Fellini, R. A., & King, M. J. (2017). 3D-printing of meso-structurally ordered carbon fiber/polymer composites with unprecedented orthotropic physical properties. Scientific Reports, 7(1), 43401. http://dx.doi.org/10.1038/srep43401. PMid:28262669.

18 Qin, C., Gong, H., Sun, C., & Wu, X. (2021). Optical properties of a core/shell/shell shape metal-insulator-metal composite nanoparticle for solar energy absorption. Engineered Science, 17, 224-230. http://dx.doi.org/10.30919/es8e509.

19 Xue, J., & Luo, Y. (2021). Sustainable food and agriculture system: a nanotechnology perspective. ES Food and Agroforestry, 5, 1-3. http://dx.doi.org/10.30919/esfaf538.

20 Silva, E. A., Ribeiro, L. A., Nascimento, M. C. B. C., & Ito, E. N. (2014). Rheological and mechanical characterization of Poly (methyl methacrylate)/silica (PMMA/SiO2) composites. Materials Research, 17(4), 926-932. http://dx.doi.org/10.1590/S1516-14392014005000114.

21 Pötschke, P., Fornes, T. D., & Paul, D. R. (2002). Rheological behavior of multiwalled carbon nanotube/polycarbonate composites. Polymer, 43(11), 3247-3255. http://dx.doi.org/10.1016/S0032-3861(02)00151-9.

22 Sun, X., Lasecki, J., Zeng, D., Gan, Y., Su, X., & Tao, J. (2015). Measurement and quantitative analysis of fiber orientation distribution in long fiber reinforced part by injection molding. Polymer Testing, 42, 168-174. http://dx.doi.org/10.1016/j.polymertesting.2015.01.016.

23 Prado, B. R., & Bartoli, J. R. (2018). Synthesis and characterization of PMMA and organic modified montmorilonites nanocomposites via in situ polymerization assisted by sonication. Applied Clay Science, 160, 132-143. http://dx.doi.org/10.1016/j.clay.2018.02.035.

24 Bressanin, J. M., Assis, V. A. Jr., & Bartoli, J. R. (2018). Electrically conductive nanocomposites of PMMA and carbon nanotubes prepared by in situ polymerization under probe sonication. Chemical Papers, 72(7), 1799-1810. http://dx.doi.org/10.1007/s11696-018-0443-5.

25 Chen, J., Zhu, Y., Guo, Z., & Nasibulin, A. G. (2020). Recent progress on thermo-electrical properties of conductive polymer composites and their application in temperature sensors. Engineered Science, 12, 13-22. http://dx.doi.org/10.30919/es8d1129.

26 Gu, H., Gao, C., Zhou, X., Du, A., Naik, N., & Guo, Z. (2021). Nanocellulose nanocomposite aerogel towards efficient oil and organic solvent adsorption. Advanced Composites and Hybrid Materials, 4(3), 459-468. http://dx.doi.org/10.1007/s42114-021-00289-y.

27 Yu, Z., Yan, Z., Zhang, F., Wang, J., Shao, Q., Murugadoss, V., Alhadhrami, A., Mersal, G. A. M., Ibrahim, M. M., El-Bahy, Z. M., Li, Y., Huang, M., & Guo, Z. (2022). Waterborne acrylic resin co-modified by itaconic acid and γ-methacryloxypropyl triisopropoxidesilane for improved mechanical properties, thermal stability, and corrosion resistance. Progress in Organic Coatings, 168, 106875. http://dx.doi.org/10.1016/j.porgcoat.2022.106875.

28 Chang, X., Chen, L., Chen, J., Zhu, Y., & Guo, Z. (2021). Advances in transparent and stretchable strain sensors. Advanced Composites and Hybrid Materials, 4(3), 435-450. http://dx.doi.org/10.1007/s42114-021-00292-3.

29 Münstedt, H., Köppl, T., & Triebel, C. (2010). Viscous and elastic properties of poly(methyl methacrylate) melts filled with silica nanoparticles. Polymer, 51(1), 185-191. http://dx.doi.org/10.1016/j.polymer.2009.11.049.

30 Triebel, C., & Münstedt, H. (2011). Temperature dependence of rheological properties of poly(methyl methacrylate) filled with silica nanoparticles. Polymer, 52(7), 1596-1602. http://dx.doi.org/10.1016/j.polymer.2011.02.014.

31 Zhang, Q., Huang, W.-X., & Zhong, G.-J. (2017). Towards transparent PMMA/SiO2 nanocomposites with promising scratch-resistance by manipulation of SiO2 aggregation followed by in situ polymerization. Journal of Applied Polymer Science, 134(12), 44612. http://dx.doi.org/10.1002/app.44612.

32 Mallakpour, S., & Naghdi, M. (2018). Polymer/SiO2 nanocomposites: production and applications. Progress in Materials Science, 97, 409-447. http://dx.doi.org/10.1016/j.pmatsci.2018.04.002.

33 Jancar, J., & Recman, L. (2010). Particle size dependence of the elastic modulus of particulate filled PMMA near its Tg. Polymer, 51(17), 3826-3828. http://dx.doi.org/10.1016/j.polymer.2010.06.041.

34 Hu, F., Li, G., Zou, P., Hu, J., Chen, S., Liu, Q., Zhang, J., Jiang, F., Wang, S., & Chi, N. (2020). 20.09-Gbit/s underwater WDM-VLC transmission based on a single Si/GaAs-substrate multichromatic LED array chip. In Optical Fiber Communication Conference (OFC) (pp. M3I.4). Washington, D.C.: Optica Publishing Group. http://dx.doi.org/10.1364/OFC.2020.M3I.4.

35 Kachere, A. R., Kakade, P. M., Kanwade, A. R., Dani, P., Mandlik, N. T., Rondiya, S. R., Dzade, N. Y., Jadkar, S. R., & Bhosale, S. V. (2022). Zinc oxide graphene oxide nanocomposites: synthesis, characterization and their optical properties. ES Materials & Manufacturing, 16, 19-29.

36 Wang, C., Wen, Y., Sun, J., & Zhou, J. (2022). Recent progress on optical frequency conversion in nonlinear metasurfaces and nanophotonics. ES Materials & Manufacturing, 17, 1-13. http://dx.doi.org/10.30919/esmm5f655.

37 Zou, D. Q., & Yoshida, H. (2010). Size effect of silica nanoparticles on thermal decomposition of PMMA. Journal of Thermal Analysis and Calorimetry, 99(1), 21-26. http://dx.doi.org/10.1007/s10973-009-0531-4.

38 Abramoff, B., & Covino, J. (1992). Transmittance and mechanical properties of PMMA-fumed silica composites. Journal of Applied Polymer Science, 46(10), 1785-1791. http://dx.doi.org/10.1002/app.1992.070461009.

39 Taurozzi, J. S., Hackley, V. A., & Wiesner, M. R. (2011). Ultrasonic dispersion of nanoparticles for environmental, health and safety assessment – issues and recommendations. Nanotoxicology, 5(4), 711-729. http://dx.doi.org/10.3109/17435390.2010.528846. PMid:21073401.

40 Price, G. J., Norris, D. J., & West, P. J. (1992). Polymerization of methyl methacrylate initiated by ultrasound. Macromolecules, 25(24), 6447-6454. http://dx.doi.org/10.1021/ma00050a010.

41 Price, G. J. (2003). Recent developments in sonochemical polymerization. Ultrasonics Sonochemistry, 10(4-5), 277-283. http://dx.doi.org/10.1016/S1350-4177(02)00156-6. PMid:12818394.

42 Kaino, T. (1985). Absorption losses of low loss plastic optical fibers. Japanese Journal of Applied Physics, 24(12R), 1661-1665. http://dx.doi.org/10.1143/JJAP.24.1661.

43 Zhu, H., Wang, Y., Qu, M., Pan, Y., Zheng, G., Dai, K., Huang, M., Alhadhrami, A., Ibrahim, M. M., El‑Bahy, Z. M., Liu, C., Shen, C., & Liu, X. (2022). Electrospun poly(vinyl alcohol)/silica film for radiative cooling. Advanced Composites and Hybrid Materials, 5(3), 1966-1975. http://dx.doi.org/10.1007/s42114-022-00529-9.

44 Si, Y., Li, J., Cui, B., Tang, D., Yang, L., Murugadoss, V., Maganti, S., Huang, M., & Guo, Z. (2022). Janus phenol–formaldehyde resin and periodic mesoporous organic silica nanoadsorbent for the removal of heavy metal ions and organic dyes from polluted water. Advanced Composites and Hybrid Materials, 5(2), 1180-1195. http://dx.doi.org/10.1007/s42114-022-00446-x.

45 Bistac, S., & Schultz, J. (1997). Solvent retention in solution-cast films of PMMA: study by dielectric spectroscopy. Progress in Organic Coatings, 31(4), 347-350. http://dx.doi.org/10.1016/S0300-9440(97)00093-3.

46 Padilha, G. S., Giacon, V. M., & Bartoli, J. R. (2017). Effect of solvents on the morphology of PMMA films fabricated by spin-coating. Polímeros: Ciência e Tecnologia, 27(3), 195-200. http://dx.doi.org/10.1590/0104-1428.12516.

47 Zhou, R.-J., & Burkhart, T. (2010). Optical properties of particle-filled polycarbonate, polystyrene, and poly(methyl methacrylate) composites. Journal of Applied Polymer Science, 115(3), 1866-1872. http://dx.doi.org/10.1002/app.31331.

48 Yu, Y.-Y., Chen, C.-Y., & Chen, W.-C. (2003). Synthesis and characterization of organic–inorganic hybrid thin films from poly(acrylic) and monodispersed colloidal silica. Polymer, 44(3), 593-601. http://dx.doi.org/10.1016/S0032-3861(02)00824-8.

49 Sunkara, H. B., Jethmalani, J. M., & Ford, W. T. (1994). Composite of colloidal crystals of silica in poly(methyl methacrylate). Chemistry of Materials, 6(4), 362-364. http://dx.doi.org/10.1021/cm00040a006.

50 van de Hulst, H. C. (1958). Light scattering by small particles. Quarterly Journal of the Royal Meteorological Society, 84(360), 198-199.

51 Zhao, J., Morgan, A. B., & Harris, J. D. (2005). Rheological characterization of polystyrene-clay nanocomposites to compare the degree of exfoliation and dispersion. Polymer, 46(20), 8641-8660. http://dx.doi.org/10.1016/j.polymer.2005.04.038.

52 Schramm, G. (2006) A practical approach to rheology and rheometry. Karlsruhe: Thermo Electron (Karlsruhe) GmbH.

53 Kotsilkova, R. (2007). Thermoset nanocomposites for engineering applications. Shawbury: Smithers Rapra Technology Limited.
 

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