Polímeros: Ciência e Tecnologia
Polímeros: Ciência e Tecnologia
Original Article

Synthesis and performance of AM/SSS/THDAB as clay hydration dispersion inhibitor

Du, Wei-Chao; Wang, Xiang-Yun; Liu, Man; Bi, Tai-Fei; Song, Shun-Xi; Zhang, Jie; Chen, Gang

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In this paper, a novel zwitterionic copolymer AM/SSS/THDAB clay hydration dispersion inhibitor was synthesized by copolymerization of tris hydroxyethyl diallyl ammonium bromide (THDAB), sodium p-styrene sulfonate (SSS) and acrylamide (AM) initiated in an aqueous solution. The copolymer was characterized by FT-IR, GPC, TGA-DSC and SEM. Results demonstrated that molecular weight of AM/SSS/THDAB was 43674 g/mol and its temperature resistance ability was up to 225 °C. Evaluation experiments showed that AM/SSS/THDAB has an excellent clay hydration inhibitive performance. Methods including particle size analysis and SEM were utilized to study its dispersion inhibition mechanism by using sodium montmorillonite (Na-MMT). Results indicated that the micro-structure of Na-MMT has been successfully changed by AM/SSS/THDAB. In a word, the superior inhibition property makes the novel clay hydration dispersion inhibitor promised in water-based drilling fluids.


clay hydration inhibitor, low molecular weight, shale gas, water-based drilling fluids.


1 Fagundes, K. R. S., Luz, R. C. S., Fagundes, F. P., & Balaban, R. C. (2018). Effect of carboxymethylcellulose on colloidal properties of calcite suspensions in drilling fluids. Polímeros: Ciência e Tecnologia28(4), 373-379. http://dx.doi.org/10.1590/0104-1428.11817

2 Chen, S. Y., Shi, Y. P., Yang, X. Y., Xie, K. Z., & Cai, J. H. (2019). Design and evaluation of a surfactant–mixed metal hydroxide-based drilling fluid for maintaining wellbore stability in coal measure strata. Energies12(10), 1862-1881. http://dx.doi.org/10.3390/en12101862

3 Wilson, M. J., & Wilson, L. (2014). Clay mineralogy and shale instability: an alternative conceptual analysis. Clay Minerals49(2), 127-145. http://dx.doi.org/10.1180/claymin.2014.049.2.01

4 Anderson, R. L., Ratcliffe, I., Greenwell, H. C., Williams, P. A., Cliffe, S., & Coveney, P. V. (2010). Clay swelling: a challenge in the oilfield. Earth-Science Reviews98(3-4), 201-216. http://dx.doi.org/10.1016/j.earscirev.2009.11.003

5 Gholami, R., Elochukwu, H., Fakhari, N., & Sarmadivaleh, M. (2018). A review on borehole instability in active shale formations: Interactions, mechanisms and inhibitors. Earth-Science Reviews177, 2-13. http://dx.doi.org/10.1016/j.earscirev.2017.11.002

6 Du, W. C., Wang, X. Y., Chen, G., Zhang, J., & Slaný, M. (2020). Synthesis, property and mechanism analysis of a novel polyhydroxy organic amine shale hydration inhibitor. Minerals10(2), 128-142. http://dx.doi.org/10.3390/min10020128

7 Rana, A., Arfaj, M. K., & Saleh, T. A. (2019). Advanced developments in shale inhibitors for oil production with low environmental footprints-A review. Fuel247, 237-249. http://dx.doi.org/10.1016/j.fuel.2019.03.006

8 Ahmed, H. M., Kamal, M. S., & Al-Harthi, M. (2019). Polymeric and low molecular weight shale inhibitors: a review. Fuel251, 187-217. http://dx.doi.org/10.1016/j.fuel.2019.04.038

9 Ghaderi, S., Ramazani S.A, A., & Haddadi, S. A. (2019). Applications of highly salt and highly temperature resistance terpolymer of acrylamide/styrene/maleic anhydride monomers as a rheological modifier: rheological and corrosion protection properties studies. Journal of Molecular Liquids294, 111635-111646. http://dx.doi.org/10.1016/j.molliq.2019.111635

10 Abdollahi, M., Pourmahdi, M., & Nasiri, A. (2018). Synthesis and characterization of lignosulfonate/acrylamide graft copolymers and their application in environmentally friendly water- based drilling fluid. Journal of Petroleum Science Engineering171, 484-494. http://dx.doi.org/10.1016/j.petrol.2018.07.065.

11 Jia, H., Huang, P., Wang, Q. X., Han, Y. G., Wang, S. Y., Zhang, F., Pan, W., & Lv, K. H. (2019). Investigation of inhibition mechanism of three deep eutectic solvents as potential shale inhibitors in water-based drilling fluids. Fuel244, 403-411. http://dx.doi.org/10.1016/j.fuel.2019.02.018

12 Zhao, X., Qiu, Z. S., Zhang, Y. J., Zhong, H. Y., Huang, W. A., & Tang, Z. C. (2017). Zwitterionic polymer P (AM-DMC-AMPS) as a low-molecular-weight encapsulator in deepwater drilling fluid. Apply. Science7(6), 594-810. http://dx.doi.org/10.3390/app7060594

13 Pu, X. L., Du, W. C., Sun, J. S., Luo, X., & Zhang, H. D. (2016). Synthesis and application of a novel polyhydroxy amine clay anti-swelling agent. Petrochemical Technology45, 595-600. 

14 Silva, F. A., Siopa, F., Figueiredo, B. F. H. T., Gonçalves, A. M. M., Pereira, J. L., Gonçalves, F., Coutinho, J. A. P., Afonso, C. A. M., & Ventura, S. P. M. (2014). Sustainable design for environment-friendly monoand dicationic cholinium-based ionic liquids. Ecotoxicology and Environmental Safety108, 302-310. http://dx.doi.org/10.1016/j.ecoenv.2014.07.003. PMid:25108510. 

15 Paz, R. A., Leite, A. M. D., Araújo, E. M., Medeiros, V. N., Melo, T. J. A., & Pessan, L. A. (2016). Mechanical and thermomechanical properties of polyamide 6/Brazilian organoclay nanocomposites. Polímeros: Ciência e Tecnologia26(1), 52-60. http://dx.doi.org/10.1590/0104-1428.1748

16 Jain, R., & Mahto, V. (2015). Evaluation of polyacrylamide/claycomposite as a potential drilling fluid additive in inhibitive water based drilling fluid system. Journal of Petroleum Science Engineering133, 612-621. http://dx.doi.org/10.1016/j.petrol.2015.07.009

17 Costa, L. P., Jr., Silva, D. B. R., Aguiar, M. F., Melo, C. P., & Alves, K. G. B. (2019). Preparation and characterization of polypyrrole/organophilicmontmorillonite nanofibers obtained by electrospinning. Journal of Molecular Liquids275, 452-462. http://dx.doi.org/10.1016/j.molliq.2018.11.084

18 Salles, F., Douillard, J.-M., Bildstein, O., Gaudin, C., Prelot, B., Zajac, J., & Van Damme, H. (2013). Driving force for the hydration of the swelling clays: case of montmorillonites saturated with alkaline-earth cations. Journal of Colloid and Interface Science395, 269-276. http://dx.doi.org/10.1016/j.jcis.2012.12.050. PMid:23352873. 

19 Boek, E. S., Coveney, P. V., & Skipper, N. T. (1995). Monte carlo molecular modeling studies of hydrated Li-, Na-,and K-smectites: understanding the role of potassium as a clay swelling inhibitor. Journal of the American Chemical Society117(50), 12608-12617. http://dx.doi.org/10.1021/ja00155a025

20 Caglar, B., Çırak, Ç., Tabak, A., Afsin, B., & Eren, E. (2013). Covalent grafting of pyridine-2-methanol into kaolinite layers. Journal of Molecular Liquids1032, 12-22. http://dx.doi.org/10.1016/j.molstruc.2012.08.004

21 Du, W. C., Pu, X. L., Sun, J. S., Luo, X., Zhang, Y. N., & Li, L. (2018). Synthesis and evaluation of a novel monomeric amine as sodium montmorillonite swelling inhibitor. Adsorption Science and Technology36(1-2), 655-668. http://dx.doi.org/10.1177/0263617417713851

22 Caglar, B., Topcu, C., Coldur, F., Sarp, G., Caglar, S., Tabak, A., & Sahin, E. (2016). Structural, thermal, morphological and surface charge properties of dodecyltrimethylammonium-smectite composites. Journal of Molecular Liquids1105, 70-79. http://dx.doi.org/10.1016/j.molstruc.2015.10.017

23 Pérez, A., Montes, M., Molina, R., & Moreno, S. (2014). Modified clays as catalysts for the catalytic oxidation of ethanol. Applied Clay Science95, 18-24. http://dx.doi.org/10.1016/j.clay.2014.02.029

24 Gang, C., Gao, L., Sun, Y., Gu, X., Hu, W., Du, W., Zhang, J., & Qu, C. (2019). A green shale inhibitor developed from lignin sulfonate and a mechanism study. Journal of Biobased Materials and Bioenergy13(6), 778-783. http://dx.doi.org/10.1166/jbmb.2019.1908

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