Mechanical, Thermal, and Barrier Properties of Methylcellulose/Cellulose Nanocrystals Nanocomposites
Silvério, Hudson Alves; Flauzino Neto, Wilson Pires; Silva, Ingrid Souza Vieira da; Rosa, Joyce Rover; Pasquini, Daniel; Assunção, Rosana M. N.; Barud, Hernane S.; Ribeiro, Sidney José Lima
http://dx.doi.org/10.1590/0104-1428.1691
Polímeros: Ciência e Tecnologia, vol.24, n6, p.683-688, 2014
Abstract
In this work, the effects of incorporating cellulose nanocrystals from soy hulls (WSH30) on the mechanical,
thermal, and barrier properties of methylcellulose (MC) nanocomposites were evaluated. MC/WSH30 nanocomposite films with different filler levels (2, 4, 6, 8, and 10%) were prepared by casting. Compared to neat MC film, improvements in the mechanical and barrier properties were observed, while thermal stability was retained. The improved mechanical properties of nanocomposites prepared may be attributed to mechanical percolation of WSH30, formation of a continuous network of WSH30 linked by hydrogen interactions and a close association between filler and matrix.
Keywords
Cellulose nanocrystals, agro-industrial residue, reinforcement, methylcellulose, nanocomposites.
References
1. Simi, C. K. & Abraham, T. E. - Colloid Polym. Sci., 288, p.297 (2010). http://dx.doi.org/10.1007/s00396-009-2151-8.
2. Khan, R. A.; Salmieri, S.; Dussault, D.; Uribe-Calderon,J.; Kamal, M. R.; Safrany, A. & Lacroix, M. - J. Agric. Food Chem., 58, p.7878 (2010). http://dx.doi.org/10.1021/jf1006853. PMid:20545366
3. Dufresne, A. - Compos. Interfaces., 10, p.369 (2003). http://dx.doi.org/10.1163/156855403771953641.
4. Flauzino Neto, W. P.; Silvério, H. A.; Dantas, N. O. & Pasquini, D. - Ind. Crops Prod., 42, p.480 (2013). http://dx.doi.org/10.1016/j.indcrop.2012.06.041.
5. Azeredo, H. M. C.; Mattoso, L. H. C.; Wood, D.; Williams, T. G.; Avena-Bustillos, R. J. & McHugh, T. H. - J. Food Sci., 74, p.N31 (2009). http://dx.doi.org/10.1111/j.1750-3841.2009.01186.x. PMid:19646052
6. Favier, V.; Canova, G. R.; Cavaillé, J. Y.; Chanzy, H.; Dufresne, A. & Gauthier, G. - Polym. Adv. Technol., 6, p.351 (1995a). http://dx.doi.org/10.1002/pat.1995.220060514.
7. Favier, V.; Chanzy, H. & Cavaillé, J. Y. - Macromolecules., 28, p.6365 (1995b). http://dx.doi.org/10.1021/ma00122a053.
8. Lin, N.; Chen, G. J.; Huang, J.; Dufresne, A. & Chang, P. R. - J. Appl. Polym. Sci., 113, p.3417 (2009). http://dx.doi.org/10.1002/app.30308.
9. Siqueira, G.; Bras, J. & Dufresne, A. - Biomacromolecules., 10, p.425 (2009). http://dx.doi.org/10.1021/bm801193d.PMid:19113881
10. Flauzino Neto, W. P.; Silvério, H. A.; Vieira, J. G.; Alves, H. C. S.; Pasquini, D.; Assunção, R. M. N. & Dantas, N. O. - Macromol. Symp., 319, p.93 (2012). http://dx.doi.org/10.1002/masy.201100194.
11. Silvério, H. A.; Flauzino Neto, W. P. & Pasquini, D. - J. Nanomater., 2013, p.1 (2013). http://dx.doi.org/10.1155/2013/289641.
12. Rimdusit, S.; Jingjid, S.; Damrongsakkul, S.; Tiptipakorn, S. & Takeichi, T. - Carbohydr. Polym., 72, p.444 (2008). http://dx.doi.org/10.1016/j.carbpol.2007.09.007.
13. Vieira, R. G. P.; Rodrigues Filho, G.; Assunção, R. M. N.; Meireles, C. S.; Vieira, J. G. & Oliveira, G. S. - Carbohydr. Polym., 67, p.182 (2007). http://dx.doi.org/10.1016/j.carbpol.2006.05.007.
14. Morelli, F. C. & Ruvolo Filho, A. - Polímeros., 20, p.121 (2010). http://dx.doi.org/10.1590/S0104-14282010005000014.
15. Tang, L. & Weder, C. - Appl. Mater. & Inter., 2, p.1073 (2010). http://dx.doi.org/10.1021/am900830h.
16. Capadona, J. R.; Shanmuganathan, K.; Tyler, D. J.; Rowan, S. J. & Weder, C. - Science., 319, p.1370 (2008). http://dx.doi.org/10.1126/science.1153307. PMid:18323449
17. Azizi Samir, M. A.; Alloin, F. & Dufresne, A. - Biomacromolecules., 6, p.612 (2005). http://dx.doi.org/10.1021/bm0493685. PMid:15762621
18. Siqueira, G.; Bras, J. & Dufresne, A. - Polymers., 2, p.728 (2010). http://dx.doi.org/10.3390/polym2040728.
19. Bindu, P. & Thomas, S. - J. Phys. Chem. B., 117, p.12632 (2013). http://dx.doi.org/10.1021/jp4039489. PMid:24090199
20. Pasquini, D.; Teixeira, E. M.; Curvelo, A. A. S.; Belgacem, M. N. & Dufresne, A. - Ind. Crops Prod., 32, p.486 (2010). http://dx.doi.org/10.1016/j.indcrop.2010.06.022.
21. Lagaron, J. M.; Catalá, R. & Gavara, R. - J . Mater. Sci. Technol., 20, p.1 (2004). http://dx.doi.org/10.1179/026708304225010442.
22. Azeredo, H. M.; Mattoso, L. H.; Avena-Bustillos, R. J. A.; Filho, G. C.; Munford, M. L.; Wood, D. & Mchugh, T. H. - J. Food Sci., 75, p.N1 (2010). http://dx.doi.org/10.1111/j.1750-3841.2009.01386.x.
23. Paralikar, S. A.; Simonsen, J. & Lombardi, J. - J. Membr. Sci., 320, p.248 (2008). http://dx.doi.org/10.1016/j.memsci.2008.04.009.
24. Sánchez-García, M. D.; Hilliou, L. & Lagarón, J. M. - J. Agric. Food Chem., 58, p.12847 (2010). http://dx.doi.org/10.1021/jf102764e. PMid:21073192
25. Moon, R. J.; Martini, A.; Nairn, J.; Simonsen, J. & Youngblood, J. - Chem. Soc. Rev., 40, p.3941 (2011). http://dx.doi.org/10.1039/c0cs00108b. PMid:21566801
26. Tang, C. & Liu, H. - Compos., Part A Appl. Sci. Manuf., 39, p.1638 (2008). http://dx.doi.org/10.1016/j.compositesa.2008.07.005.
27. Etang Ayuk, J.; Mathew, A. P. & Oksman, K. - J. Appl. Polym. Sci., 114, p.2723 (2009). http://dx.doi.org/10.1002/app.30583.
28. Roman, M. & Winter, W. T. - Biomacromolecules., 5, p.1671 (2004). http://dx.doi.org/10.1021/bm034519+.PMid:15360274
2. Khan, R. A.; Salmieri, S.; Dussault, D.; Uribe-Calderon,J.; Kamal, M. R.; Safrany, A. & Lacroix, M. - J. Agric. Food Chem., 58, p.7878 (2010). http://dx.doi.org/10.1021/jf1006853. PMid:20545366
3. Dufresne, A. - Compos. Interfaces., 10, p.369 (2003). http://dx.doi.org/10.1163/156855403771953641.
4. Flauzino Neto, W. P.; Silvério, H. A.; Dantas, N. O. & Pasquini, D. - Ind. Crops Prod., 42, p.480 (2013). http://dx.doi.org/10.1016/j.indcrop.2012.06.041.
5. Azeredo, H. M. C.; Mattoso, L. H. C.; Wood, D.; Williams, T. G.; Avena-Bustillos, R. J. & McHugh, T. H. - J. Food Sci., 74, p.N31 (2009). http://dx.doi.org/10.1111/j.1750-3841.2009.01186.x. PMid:19646052
6. Favier, V.; Canova, G. R.; Cavaillé, J. Y.; Chanzy, H.; Dufresne, A. & Gauthier, G. - Polym. Adv. Technol., 6, p.351 (1995a). http://dx.doi.org/10.1002/pat.1995.220060514.
7. Favier, V.; Chanzy, H. & Cavaillé, J. Y. - Macromolecules., 28, p.6365 (1995b). http://dx.doi.org/10.1021/ma00122a053.
8. Lin, N.; Chen, G. J.; Huang, J.; Dufresne, A. & Chang, P. R. - J. Appl. Polym. Sci., 113, p.3417 (2009). http://dx.doi.org/10.1002/app.30308.
9. Siqueira, G.; Bras, J. & Dufresne, A. - Biomacromolecules., 10, p.425 (2009). http://dx.doi.org/10.1021/bm801193d.PMid:19113881
10. Flauzino Neto, W. P.; Silvério, H. A.; Vieira, J. G.; Alves, H. C. S.; Pasquini, D.; Assunção, R. M. N. & Dantas, N. O. - Macromol. Symp., 319, p.93 (2012). http://dx.doi.org/10.1002/masy.201100194.
11. Silvério, H. A.; Flauzino Neto, W. P. & Pasquini, D. - J. Nanomater., 2013, p.1 (2013). http://dx.doi.org/10.1155/2013/289641.
12. Rimdusit, S.; Jingjid, S.; Damrongsakkul, S.; Tiptipakorn, S. & Takeichi, T. - Carbohydr. Polym., 72, p.444 (2008). http://dx.doi.org/10.1016/j.carbpol.2007.09.007.
13. Vieira, R. G. P.; Rodrigues Filho, G.; Assunção, R. M. N.; Meireles, C. S.; Vieira, J. G. & Oliveira, G. S. - Carbohydr. Polym., 67, p.182 (2007). http://dx.doi.org/10.1016/j.carbpol.2006.05.007.
14. Morelli, F. C. & Ruvolo Filho, A. - Polímeros., 20, p.121 (2010). http://dx.doi.org/10.1590/S0104-14282010005000014.
15. Tang, L. & Weder, C. - Appl. Mater. & Inter., 2, p.1073 (2010). http://dx.doi.org/10.1021/am900830h.
16. Capadona, J. R.; Shanmuganathan, K.; Tyler, D. J.; Rowan, S. J. & Weder, C. - Science., 319, p.1370 (2008). http://dx.doi.org/10.1126/science.1153307. PMid:18323449
17. Azizi Samir, M. A.; Alloin, F. & Dufresne, A. - Biomacromolecules., 6, p.612 (2005). http://dx.doi.org/10.1021/bm0493685. PMid:15762621
18. Siqueira, G.; Bras, J. & Dufresne, A. - Polymers., 2, p.728 (2010). http://dx.doi.org/10.3390/polym2040728.
19. Bindu, P. & Thomas, S. - J. Phys. Chem. B., 117, p.12632 (2013). http://dx.doi.org/10.1021/jp4039489. PMid:24090199
20. Pasquini, D.; Teixeira, E. M.; Curvelo, A. A. S.; Belgacem, M. N. & Dufresne, A. - Ind. Crops Prod., 32, p.486 (2010). http://dx.doi.org/10.1016/j.indcrop.2010.06.022.
21. Lagaron, J. M.; Catalá, R. & Gavara, R. - J . Mater. Sci. Technol., 20, p.1 (2004). http://dx.doi.org/10.1179/026708304225010442.
22. Azeredo, H. M.; Mattoso, L. H.; Avena-Bustillos, R. J. A.; Filho, G. C.; Munford, M. L.; Wood, D. & Mchugh, T. H. - J. Food Sci., 75, p.N1 (2010). http://dx.doi.org/10.1111/j.1750-3841.2009.01386.x.
23. Paralikar, S. A.; Simonsen, J. & Lombardi, J. - J. Membr. Sci., 320, p.248 (2008). http://dx.doi.org/10.1016/j.memsci.2008.04.009.
24. Sánchez-García, M. D.; Hilliou, L. & Lagarón, J. M. - J. Agric. Food Chem., 58, p.12847 (2010). http://dx.doi.org/10.1021/jf102764e. PMid:21073192
25. Moon, R. J.; Martini, A.; Nairn, J.; Simonsen, J. & Youngblood, J. - Chem. Soc. Rev., 40, p.3941 (2011). http://dx.doi.org/10.1039/c0cs00108b. PMid:21566801
26. Tang, C. & Liu, H. - Compos., Part A Appl. Sci. Manuf., 39, p.1638 (2008). http://dx.doi.org/10.1016/j.compositesa.2008.07.005.
27. Etang Ayuk, J.; Mathew, A. P. & Oksman, K. - J. Appl. Polym. Sci., 114, p.2723 (2009). http://dx.doi.org/10.1002/app.30583.
28. Roman, M. & Winter, W. T. - Biomacromolecules., 5, p.1671 (2004). http://dx.doi.org/10.1021/bm034519+.PMid:15360274
Facebook
Google+
Twitter
LinkedIn
Mendeley
StumbleUpon
CiteULike
Reddit
Email