Polímeros: Ciência e Tecnologia
https://revistapolimeros.org.br/article/doi/10.4322/polimeros.2013.095
Polímeros: Ciência e Tecnologia
Standards and Methods

Correlation Between Onset Oxidation Temperature (OOT) and Fourier Transform Infrared Spectroscopy (FTIR) for Monitoring the Restabilization of Recycled Low-density Polyethylene (LDPE)

Ruvolo Filho, Adhemar; Pelozzi, Tadeu Luiz A.

Downloads: 0
Views: 1156

Abstract

In this work a new method was developed for monitoring the oxidative stability of restabilized and nonrestabilized low-density polyethylene (LDPE) during multiple extrusion cycles. The method is based on correlations between Fourier Transform Infrared spectroscopy (FTIR) and Onset Oxidation Temperature (OOT). Non-linear calibration curves correlating the concentration of primary or secondary antioxidants and the OOT values were obtained.

Keywords

Recycling of LDPE, thermogravimetry, FTIR, restabilization, primary antioxidants, secondary antioxidants

References



1. La Mantia, F. P. - “Basic concepts in plastics recycling”, in: Recycling of PVC and mixed plastics, La Mantia FP ed., Chem. Tec., Toronto (1996).

2. Chen, C. & Lai, F. S. - Polym. Eng. Sci., 34, p.472 (1994). http://dx.doi.org/10.1002/pen.760340603

3. Dimitrova, T. L.; La Mantia, F. P.; Pilati, F.; Toselli, M.; Valenza, A. & Visco, A. - Polymer, 41, p.4817 (2000). http://dx.doi.org/10.1016/S0032-3861(99)00709-0

4. Pluta, M.; Bartczak, Z.; Pawlak, A.; Galeski, A. & Pracella, M. - J. Appl. Polym. Sci., 82, p.1423 (2001). http://dx.doi. org/10.1002/app.1980

5. Ruvolo-Filho, A. & Marconcini, J. M. - Mat. Res., 10, p.341 (2007). http://dx.doi.org/10.1590/S1516- 14392007000400004

6. Sadrmohaghegh, C. & Scott, G. - Eur. Polym. J., 16, p.1037 (1980). http://dx.doi.org/10.1016/0014-3057(80)90220-7

7. Kyriakou, S. A.; Statherpoulos, M.; Parissakis, G K.; Papaspyrides, C. D. & Kartalis, C. N. - Polym. Degrad. Stabil., 66, p.49 (1999). http://dx.doi.org/10.1016/S0141- 3910(99)00051-8

8. Moss, S. & Zweifel, H. - Polym. Degrad. Stabil., 25, p.217 (1989). http://dx.doi.org/10.1016/S0141-3910(89)81009-2

9. Chen, Y. L. & Ranby, B. - J. P. Sci., part A, 28, p.1847 (1990). http://dx.doi.org/10.1002/pola.1990.080280717

10. Uhniat, M. & Latocha, C. - Polym. Degrad. Stabil., 35, p.163 (1992). http://dx.doi.org/10.1016/0141-3910(92)90108-H
588371997f8c9d0a0c8b4996 polimeros Articles
Links & Downloads

Polímeros: Ciência e Tecnologia

Share this page
Page Sections